Enantioselective iridium-catalyzed allylation of sodium benzotriazolide: An efficient way to chiral allylbenzotriazoles

Min Zhang; Xin Wen Guo; Sheng Cai Zheng; Xiao Ming Zhao

doi:10.1016/j.tetlet.2012.10.064

Enantioselective iridium-catalyzed allylation of sodium benzotriazolide: An efficient way to chiral allylbenzotriazoles

Min Zhang
, Xin Wen Guo
, Sheng Cai Zheng
, Xiao Ming Zhao^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A highly enantioselective allylic substitution of sodium benzotriazolide has been attained in the presence of [Ir(COD)Cl]₂/phosphoramidite ligand L1 together with K₃PO₄ as an additive, producing enantioenriched allylbenzotriazole compounds with up to 98% ee.

Original language	English
Pages (from-to)	6995-6998
Number of pages	4
Journal	Tetrahedron Letters
Volume	53
Issue number	51
DOIs	https://doi.org/10.1016/j.tetlet.2012.10.064
State	Published - 19 Dec 2012
Externally published	Yes

Keywords

Asymmetric allylation
Iridium
Phosphoramidite ligand
Sodium benzotriazolide

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10.1016/j.tetlet.2012.10.064

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title = "Enantioselective iridium-catalyzed allylation of sodium benzotriazolide: An efficient way to chiral allylbenzotriazoles",

abstract = "A highly enantioselective allylic substitution of sodium benzotriazolide has been attained in the presence of [Ir(COD)Cl]2/phosphoramidite ligand L1 together with K3PO4 as an additive, producing enantioenriched allylbenzotriazole compounds with up to 98\% ee.",

keywords = "Asymmetric allylation, Iridium, Phosphoramidite ligand, Sodium benzotriazolide",

author = "Min Zhang and Guo, \{Xin Wen\} and Zheng, \{Sheng Cai\} and Zhao, \{Xiao Ming\}",

year = "2012",

month = dec,

day = "19",

doi = "10.1016/j.tetlet.2012.10.064",

language = "英语",

volume = "53",

pages = "6995--6998",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

number = "51",

}

TY - JOUR

T1 - Enantioselective iridium-catalyzed allylation of sodium benzotriazolide

T2 - An efficient way to chiral allylbenzotriazoles

AU - Zhang, Min

AU - Guo, Xin Wen

AU - Zheng, Sheng Cai

AU - Zhao, Xiao Ming

PY - 2012/12/19

Y1 - 2012/12/19

N2 - A highly enantioselective allylic substitution of sodium benzotriazolide has been attained in the presence of [Ir(COD)Cl]2/phosphoramidite ligand L1 together with K3PO4 as an additive, producing enantioenriched allylbenzotriazole compounds with up to 98% ee.

AB - A highly enantioselective allylic substitution of sodium benzotriazolide has been attained in the presence of [Ir(COD)Cl]2/phosphoramidite ligand L1 together with K3PO4 as an additive, producing enantioenriched allylbenzotriazole compounds with up to 98% ee.

KW - Asymmetric allylation

KW - Iridium

KW - Phosphoramidite ligand

KW - Sodium benzotriazolide

UR - https://www.scopus.com/pages/publications/84869207237

U2 - 10.1016/j.tetlet.2012.10.064

DO - 10.1016/j.tetlet.2012.10.064

M3 - 文章

AN - SCOPUS:84869207237

SN - 0040-4039

VL - 53

SP - 6995

EP - 6998

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 51

ER -

Enantioselective iridium-catalyzed allylation of sodium benzotriazolide: An efficient way to chiral allylbenzotriazoles

Abstract

Keywords

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