Enantioselective gold-catalyzed intermolecular [2 + 2]-cycloadditions of 3-styrylindoles with: N -allenyl oxazolidinone

Haoxiang Hu; Yidong Wang; Deyun Qian; Zhan Ming Zhang; Lu Liu; Junliang Zhang

doi:10.1039/c6qo00087h

Enantioselective gold-catalyzed intermolecular [2 + 2]-cycloadditions of 3-styrylindoles with: N -allenyl oxazolidinone

Haoxiang Hu
, Yidong Wang
, Deyun Qian
, Zhan Ming Zhang
, Lu Liu^*
, Junliang Zhang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

63 Scopus citations

Abstract

The enantioselective intermolecular [2 + 2] cycloaddition of 3-styrylindoles with N-allenyl oxazolidinone has been achieved for the first time by the employment of a Xiang-Phos derived chiral gold-catalyst. The corresponding cycloadducts could be obtained in good yields (up to 95%) with up to 95% ee.

Original language	English
Pages (from-to)	759-763
Number of pages	5
Journal	Organic Chemistry Frontiers
Volume	3
Issue number	6
DOIs	https://doi.org/10.1039/c6qo00087h
State	Published - 2016

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title = "Enantioselective gold-catalyzed intermolecular [2 + 2]-cycloadditions of 3-styrylindoles with: N -allenyl oxazolidinone",

abstract = "The enantioselective intermolecular [2 + 2] cycloaddition of 3-styrylindoles with N-allenyl oxazolidinone has been achieved for the first time by the employment of a Xiang-Phos derived chiral gold-catalyst. The corresponding cycloadducts could be obtained in good yields (up to 95\%) with up to 95\% ee.",

author = "Haoxiang Hu and Yidong Wang and Deyun Qian and Zhang, \{Zhan Ming\} and Lu Liu and Junliang Zhang",

note = "Publisher Copyright: {\textcopyright} 2016 the Partner Organisations.",

year = "2016",

doi = "10.1039/c6qo00087h",

language = "英语",

volume = "3",

pages = "759--763",

journal = "Organic Chemistry Frontiers",

issn = "2052-4110",

publisher = "Royal Society of Chemistry",

number = "6",

}

TY - JOUR

T1 - Enantioselective gold-catalyzed intermolecular [2 + 2]-cycloadditions of 3-styrylindoles with

T2 - N -allenyl oxazolidinone

AU - Hu, Haoxiang

AU - Wang, Yidong

AU - Qian, Deyun

AU - Zhang, Zhan Ming

AU - Liu, Lu

AU - Zhang, Junliang

PY - 2016

Y1 - 2016

N2 - The enantioselective intermolecular [2 + 2] cycloaddition of 3-styrylindoles with N-allenyl oxazolidinone has been achieved for the first time by the employment of a Xiang-Phos derived chiral gold-catalyst. The corresponding cycloadducts could be obtained in good yields (up to 95%) with up to 95% ee.

AB - The enantioselective intermolecular [2 + 2] cycloaddition of 3-styrylindoles with N-allenyl oxazolidinone has been achieved for the first time by the employment of a Xiang-Phos derived chiral gold-catalyst. The corresponding cycloadducts could be obtained in good yields (up to 95%) with up to 95% ee.

UR - https://www.scopus.com/pages/publications/84971655180

U2 - 10.1039/c6qo00087h

DO - 10.1039/c6qo00087h

M3 - 文章

AN - SCOPUS:84971655180

SN - 2052-4110

VL - 3

SP - 759

EP - 763

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 6

ER -

Enantioselective gold-catalyzed intermolecular [2 + 2]-cycloadditions of 3-styrylindoles with: N -allenyl oxazolidinone

Abstract

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