Enantioselective domino reaction of CO2, amines and allyl chlorides under iridium catalysis: Formation of allyl carbamates

Min Zhang; Xiaoming Zhao; Shengcai Zheng

doi:10.1039/c4cc00413b

Enantioselective domino reaction of CO₂, amines and allyl chlorides under iridium catalysis: Formation of allyl carbamates

Min Zhang, Xiaoming Zhao, Shengcai Zheng

Tongji University

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

The enantioselective domino reaction between CO₂ (1 atm), amines and linear allyl chlorides in the presence of an iridium complex, DABCO and toluene at 15 °C was realized, which gave branched allyl carbamates in acceptable to high yields with up to excellent regioselectivity (99/1) and 94% ee. This is the first example of the synthesis of chiral allyl carbamates through catalytic domino reactions using CO₂. This journal is

Original language	English
Pages (from-to)	4455-4458
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	34
DOIs	https://doi.org/10.1039/c4cc00413b
State	Published - 4 May 2014
Externally published	Yes

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abstract = "The enantioselective domino reaction between CO2 (1 atm), amines and linear allyl chlorides in the presence of an iridium complex, DABCO and toluene at 15 °C was realized, which gave branched allyl carbamates in acceptable to high yields with up to excellent regioselectivity (99/1) and 94\% ee. This is the first example of the synthesis of chiral allyl carbamates through catalytic domino reactions using CO2. This journal is",

author = "Min Zhang and Xiaoming Zhao and Shengcai Zheng",

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doi = "10.1039/c4cc00413b",

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T2 - Formation of allyl carbamates

AU - Zhang, Min

AU - Zhao, Xiaoming

AU - Zheng, Shengcai

PY - 2014/5/4

Y1 - 2014/5/4

N2 - The enantioselective domino reaction between CO2 (1 atm), amines and linear allyl chlorides in the presence of an iridium complex, DABCO and toluene at 15 °C was realized, which gave branched allyl carbamates in acceptable to high yields with up to excellent regioselectivity (99/1) and 94% ee. This is the first example of the synthesis of chiral allyl carbamates through catalytic domino reactions using CO2. This journal is

AB - The enantioselective domino reaction between CO2 (1 atm), amines and linear allyl chlorides in the presence of an iridium complex, DABCO and toluene at 15 °C was realized, which gave branched allyl carbamates in acceptable to high yields with up to excellent regioselectivity (99/1) and 94% ee. This is the first example of the synthesis of chiral allyl carbamates through catalytic domino reactions using CO2. This journal is

UR - https://www.scopus.com/pages/publications/84897507515

U2 - 10.1039/c4cc00413b

DO - 10.1039/c4cc00413b

M3 - 文章

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Enantioselective domino reaction of CO₂, amines and allyl chlorides under iridium catalysis: Formation of allyl carbamates

Abstract

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