Enantioselective carboxylative cyclization of propargylic alcohol with carbon dioxide under mild conditions

Shiliang Xie; Xiaotong Gao; Feng Zhou; Haihong Wu; Jian Zhou

doi:10.1016/j.cclet.2019.05.060

Enantioselective carboxylative cyclization of propargylic alcohol with carbon dioxide under mild conditions

Shiliang Xie
, Xiaotong Gao
, Feng Zhou^*
, Haihong Wu
, Jian Zhou

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University
CAS - Shanghai Institute of Organic Chemistry

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

An enantioselective carboxylative cyclization of propargylic alcohols and CO₂ was realized under mild conditions, based on a kinetic resolution strategy, which enabled the synthesis of chiral cyclic carbonates and propargylic alcohols with promising yield and enantioselectivity simultaneously.

Original language	English
Pages (from-to)	324-328
Number of pages	5
Journal	Chinese Chemical Letters
Volume	31
Issue number	2
DOIs	https://doi.org/10.1016/j.cclet.2019.05.060
State	Published - Feb 2020

Keywords

Carbon dioxide
Cyclic carbonates
Kinetic resolution
Propargylic alcohols

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10.1016/j.cclet.2019.05.060

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title = "Enantioselective carboxylative cyclization of propargylic alcohol with carbon dioxide under mild conditions",

abstract = "An enantioselective carboxylative cyclization of propargylic alcohols and CO2 was realized under mild conditions, based on a kinetic resolution strategy, which enabled the synthesis of chiral cyclic carbonates and propargylic alcohols with promising yield and enantioselectivity simultaneously.",

keywords = "Carbon dioxide, Cyclic carbonates, Kinetic resolution, Propargylic alcohols",

author = "Shiliang Xie and Xiaotong Gao and Feng Zhou and Haihong Wu and Jian Zhou",

note = "Publisher Copyright: {\textcopyright} 2020 The Author",

year = "2020",

month = feb,

doi = "10.1016/j.cclet.2019.05.060",

language = "英语",

volume = "31",

pages = "324--328",

journal = "Chinese Chemical Letters",

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T1 - Enantioselective carboxylative cyclization of propargylic alcohol with carbon dioxide under mild conditions

AU - Xie, Shiliang

AU - Gao, Xiaotong

AU - Zhou, Feng

AU - Wu, Haihong

AU - Zhou, Jian

PY - 2020/2

Y1 - 2020/2

N2 - An enantioselective carboxylative cyclization of propargylic alcohols and CO2 was realized under mild conditions, based on a kinetic resolution strategy, which enabled the synthesis of chiral cyclic carbonates and propargylic alcohols with promising yield and enantioselectivity simultaneously.

AB - An enantioselective carboxylative cyclization of propargylic alcohols and CO2 was realized under mild conditions, based on a kinetic resolution strategy, which enabled the synthesis of chiral cyclic carbonates and propargylic alcohols with promising yield and enantioselectivity simultaneously.

KW - Carbon dioxide

KW - Cyclic carbonates

KW - Kinetic resolution

KW - Propargylic alcohols

UR - https://www.scopus.com/pages/publications/85067994235

U2 - 10.1016/j.cclet.2019.05.060

DO - 10.1016/j.cclet.2019.05.060

M3 - 文章

AN - SCOPUS:85067994235

SN - 1001-8417

VL - 31

SP - 324

EP - 328

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 2

ER -

Enantioselective carboxylative cyclization of propargylic alcohol with carbon dioxide under mild conditions

Abstract

Keywords

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