Electrosorptive desalination by carbon nanotubes and nanofibres electrodes and ion-exchange membranes

  • Haibo Li
  • , Yang Gao
  • , Likun Pan*
  • , Yanping Zhang
  • , Yiwei Chen
  • , Zhuo Sun
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

323 Scopus citations

Abstract

A novel membrane capacitive deionization (MCDI) device, integrating both the advantages of carbon nanotubes and carbon nanofibers (CNTs-CNFs) composite film and ion-exchange membrane, was proposed with high removal efficiency, low energy consumption and low cost. The CNTs-CNFs film was synthesized by low pressure and low temperature thermal chemical vapor deposition. Several experiments were conducted to compare desalination performance of MCDI with capacitive deionization (CDI), showing that salt removal of the MCDI system was 49.2% higher than that of the CDI system. The electrosorption isotherms of MCDI and CDI show both of them follow Langmuir adsorption, indicating no change in adsorption behavior when ion-exchange membranes are introduced into CDI system. The better desalination performance of MCDI than that of CDI is due to the minimized ion desorption during electrosorption.

Original languageEnglish
Pages (from-to)4923-4928
Number of pages6
JournalWater Research
Volume42
Issue number20
DOIs
StatePublished - Dec 2008
Externally publishedYes

Keywords

  • Capacitive deionization
  • Carbon nanotubes and nanofibres
  • Electrosorption
  • Ion-exchange membrane

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