Electron transfer theory revisited: Quantum solvation effect

Ping Han; Rui Xue Xt; Ping Gui; Yan Mo; Guozhong He; Yijing Yan

doi:10.1142/S0219633606002477

Electron transfer theory revisited: Quantum solvation effect

Ping Han^*, Rui Xue Xt, Ping Gui, Yan Mo, Guozhong He, Yijing Yan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The effect of solvation on ET rate processes has been investigated on the basis of the exact theory constructed in J. Phys. Chem. B 110:11438, 2006. The nature of solvation has been studied in close relation with the mechanism of ET processes. The resulting Kramers' turnover and Marcus' inversion characteristics have been analyzed accordingly. The classical picture of solvation has been found to be invalid when the solvent longitudinal relaxation time is short compared with the inverse temperature.

Original language	English
Pages (from-to)	685-692
Number of pages	8
Journal	Journal of Theoretical and Computational Chemistry
Volume	5
Issue number	3
DOIs	https://doi.org/10.1142/S0219633606002477
State	Published - Sep 2006
Externally published	Yes

Keywords

Electron transfer
Quantum dissipation
Quantum solvation

Access to Document

10.1142/S0219633606002477

Cite this

@article{a6cb1375a3a748dbbe6e6eaf76f663e5,

title = "Electron transfer theory revisited: Quantum solvation effect",

abstract = "The effect of solvation on ET rate processes has been investigated on the basis of the exact theory constructed in J. Phys. Chem. B 110:11438, 2006. The nature of solvation has been studied in close relation with the mechanism of ET processes. The resulting Kramers' turnover and Marcus' inversion characteristics have been analyzed accordingly. The classical picture of solvation has been found to be invalid when the solvent longitudinal relaxation time is short compared with the inverse temperature.",

keywords = "Electron transfer, Quantum dissipation, Quantum solvation",

author = "Ping Han and Xt, \{Rui Xue\} and Ping Gui and Yan Mo and Guozhong He and Yijing Yan",

year = "2006",

month = sep,

doi = "10.1142/S0219633606002477",

language = "英语",

volume = "5",

pages = "685--692",

journal = "Journal of Theoretical and Computational Chemistry",

issn = "0219-6336",

publisher = "World Scientific",

number = "3",

}

TY - JOUR

T1 - Electron transfer theory revisited

T2 - Quantum solvation effect

AU - Han, Ping

AU - Xt, Rui Xue

AU - Gui, Ping

AU - Mo, Yan

AU - He, Guozhong

AU - Yan, Yijing

PY - 2006/9

Y1 - 2006/9

N2 - The effect of solvation on ET rate processes has been investigated on the basis of the exact theory constructed in J. Phys. Chem. B 110:11438, 2006. The nature of solvation has been studied in close relation with the mechanism of ET processes. The resulting Kramers' turnover and Marcus' inversion characteristics have been analyzed accordingly. The classical picture of solvation has been found to be invalid when the solvent longitudinal relaxation time is short compared with the inverse temperature.

AB - The effect of solvation on ET rate processes has been investigated on the basis of the exact theory constructed in J. Phys. Chem. B 110:11438, 2006. The nature of solvation has been studied in close relation with the mechanism of ET processes. The resulting Kramers' turnover and Marcus' inversion characteristics have been analyzed accordingly. The classical picture of solvation has been found to be invalid when the solvent longitudinal relaxation time is short compared with the inverse temperature.

KW - Electron transfer

KW - Quantum dissipation

KW - Quantum solvation

UR - https://www.scopus.com/pages/publications/33749349792

U2 - 10.1142/S0219633606002477

DO - 10.1142/S0219633606002477

M3 - 文章

AN - SCOPUS:33749349792

SN - 0219-6336

VL - 5

SP - 685

EP - 692

JO - Journal of Theoretical and Computational Chemistry

JF - Journal of Theoretical and Computational Chemistry

IS - 3

ER -

Electron transfer theory revisited: Quantum solvation effect

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this