Electromechanical properties of (Ba,Sr)(Zr,Ti)O3 ceramics

Yao Li; Hongbo Cheng; Huiwen Xu; Yunxiang Zhang; Peng Yan; Ting Huang; Chunming Wang; Zhigao Hu; Jun Ouyang

doi:10.1016/j.ceramint.2016.03.137

Electromechanical properties of (Ba,Sr)(Zr,Ti)O₃ ceramics

Yao Li
, Hongbo Cheng
, Huiwen Xu
, Yunxiang Zhang
, Peng Yan
, Ting Huang
, Chunming Wang
, Zhigao Hu
, Jun Ouyang^*

^*Corresponding author for this work

School of Physics and Electronic Science

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

In this work, we report dielectric, piezoelectric and ferroelectric properties of perovskite Ba_0.95Sr_0.05Zr_xTi_(1-x)O₃ (BSZT, x=0.05, 0.10, 0.15, 0.20) ceramics synthesized by using a solid-state reaction method. It is demonstrated that when the Zr concentration was 5 at% and the sintering temperature was 1400 °C, the BSZT ceramic gives the best overall electromechanical performance, including a large remnant polarization of ∼ 12.1 μC/cm², large dielectric constants (ϵrpeak≈12,600, ϵrRT≈3500) and an excellent d₃₃ value of ∼355 pC/N. Curie temperature of this ceramic is about ∼100 °C. The enhanced electromechanical properties of the BSZT ceramics as compared with Ba_0.95Sr_0.05TiO₃ (BST) can be explained by optimization of the tolerance factor and shift of ferroelectric polymorphic phase transition temperatures (T_PPT).

Original language	English
Pages (from-to)	10191-10196
Number of pages	6
Journal	Ceramics International
Volume	42
Issue number	8
DOIs	https://doi.org/10.1016/j.ceramint.2016.03.137
State	Published - 1 Jun 2016

Keywords

Barium titanate
Lead-free piezoceramics
Phase structure
Piezoelectricity
Polymorphic phase transition

Access to Document

10.1016/j.ceramint.2016.03.137

Cite this

@article{7fdcc020c7464f8c868e2da213f074b8,

title = "Electromechanical properties of (Ba,Sr)(Zr,Ti)O3 ceramics",

abstract = "In this work, we report dielectric, piezoelectric and ferroelectric properties of perovskite Ba0.95Sr0.05ZrxTi(1-x)O3 (BSZT, x=0.05, 0.10, 0.15, 0.20) ceramics synthesized by using a solid-state reaction method. It is demonstrated that when the Zr concentration was 5 at\% and the sintering temperature was 1400 °C, the BSZT ceramic gives the best overall electromechanical performance, including a large remnant polarization of ∼ 12.1 μC/cm2, large dielectric constants (ϵrpeak≈12,600, ϵrRT≈3500) and an excellent d33 value of ∼355 pC/N. Curie temperature of this ceramic is about ∼100 °C. The enhanced electromechanical properties of the BSZT ceramics as compared with Ba0.95Sr0.05TiO3 (BST) can be explained by optimization of the tolerance factor and shift of ferroelectric polymorphic phase transition temperatures (TPPT).",

keywords = "Barium titanate, Lead-free piezoceramics, Phase structure, Piezoelectricity, Polymorphic phase transition",

author = "Yao Li and Hongbo Cheng and Huiwen Xu and Yunxiang Zhang and Peng Yan and Ting Huang and Chunming Wang and Zhigao Hu and Jun Ouyang",

year = "2016",

month = jun,

day = "1",

doi = "10.1016/j.ceramint.2016.03.137",

language = "英语",

volume = "42",

pages = "10191--10196",

journal = "Ceramics International",

issn = "0272-8842",

publisher = "Elsevier Ltd",

number = "8",

}

TY - JOUR

T1 - Electromechanical properties of (Ba,Sr)(Zr,Ti)O3 ceramics

AU - Li, Yao

AU - Cheng, Hongbo

AU - Xu, Huiwen

AU - Zhang, Yunxiang

AU - Yan, Peng

AU - Huang, Ting

AU - Wang, Chunming

AU - Hu, Zhigao

AU - Ouyang, Jun

PY - 2016/6/1

Y1 - 2016/6/1

N2 - In this work, we report dielectric, piezoelectric and ferroelectric properties of perovskite Ba0.95Sr0.05ZrxTi(1-x)O3 (BSZT, x=0.05, 0.10, 0.15, 0.20) ceramics synthesized by using a solid-state reaction method. It is demonstrated that when the Zr concentration was 5 at% and the sintering temperature was 1400 °C, the BSZT ceramic gives the best overall electromechanical performance, including a large remnant polarization of ∼ 12.1 μC/cm2, large dielectric constants (ϵrpeak≈12,600, ϵrRT≈3500) and an excellent d33 value of ∼355 pC/N. Curie temperature of this ceramic is about ∼100 °C. The enhanced electromechanical properties of the BSZT ceramics as compared with Ba0.95Sr0.05TiO3 (BST) can be explained by optimization of the tolerance factor and shift of ferroelectric polymorphic phase transition temperatures (TPPT).

AB - In this work, we report dielectric, piezoelectric and ferroelectric properties of perovskite Ba0.95Sr0.05ZrxTi(1-x)O3 (BSZT, x=0.05, 0.10, 0.15, 0.20) ceramics synthesized by using a solid-state reaction method. It is demonstrated that when the Zr concentration was 5 at% and the sintering temperature was 1400 °C, the BSZT ceramic gives the best overall electromechanical performance, including a large remnant polarization of ∼ 12.1 μC/cm2, large dielectric constants (ϵrpeak≈12,600, ϵrRT≈3500) and an excellent d33 value of ∼355 pC/N. Curie temperature of this ceramic is about ∼100 °C. The enhanced electromechanical properties of the BSZT ceramics as compared with Ba0.95Sr0.05TiO3 (BST) can be explained by optimization of the tolerance factor and shift of ferroelectric polymorphic phase transition temperatures (TPPT).

KW - Barium titanate

KW - Lead-free piezoceramics

KW - Phase structure

KW - Piezoelectricity

KW - Polymorphic phase transition

UR - https://www.scopus.com/pages/publications/84963682369

U2 - 10.1016/j.ceramint.2016.03.137

DO - 10.1016/j.ceramint.2016.03.137

M3 - 文章

AN - SCOPUS:84963682369

SN - 0272-8842

VL - 42

SP - 10191

EP - 10196

JO - Ceramics International

JF - Ceramics International

IS - 8

ER -

Electromechanical properties of (Ba,Sr)(Zr,Ti)O₃ ceramics

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this