Electrochemic growth of CuInSe2 thin film on ITO/soda-lime glass from acidic medium

N. J. Yao; S. M. Huang; L. K. Pan; Z. Sun; Y. W. Chen

doi:10.1109/INEC.2008.4585593

Electrochemic growth of CuInSe₂ thin film on ITO/soda-lime glass from acidic medium

N. J. Yao
, S. M. Huang
, L. K. Pan
, Z. Sun
, Y. W. Chen

East China Normal University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Scopus citations

Abstract

The simultaneous electrodeposition of the Cu-In-Se system was investigated. The study was carried out at pH 1.8 using Sodium citrate as completing agent for the Cu²⁺ ion. The synthesis of CuInSe₂ semiconductor thin film was carried out by electrodeposition on indium-tin oxide (ITO) /soda-lime glass. The simultaneous codeposition of the Cu, In, and Se was achieved by constant potential electrolysis technique in aqueous solutions containing CuCl₂, InCl₃, and H₂SeO₃. The as-deposited and annealed films were characterized by scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy (EDX), x-ray diffraction (XRD), and Raman spectroscopy. Homogeneous films were deposited with a well-defined composition and chalcopyrite structure. The crystallinity of the films was improved by annealing. The deposited stoichiometric CuInSe₂ layers were about 2 μm in thickness. The annealed film is with a perfect crystallized and single chalcopyrite structure. It is suitable for photovoltaic applications.

Original language	English
Title of host publication	2008 2nd IEEE International Nanoelectronics Conference, INEC 2008
Pages	751-754
Number of pages	4
DOIs	https://doi.org/10.1109/INEC.2008.4585593
State	Published - 2008
Externally published	Yes
Event	2008 2nd IEEE International Nanoelectronics Conference, INEC 2008 - Shanghai, China Duration: 24 Mar 2008 → 27 Mar 2008

Publication series

Name	2008 2nd IEEE International Nanoelectronics Conference, INEC 2008

Conference

Conference	2008 2nd IEEE International Nanoelectronics Conference, INEC 2008
Country/Territory	China
City	Shanghai
Period	24/03/08 → 27/03/08

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Chalcopyrite
CuInSe (CIS)
Electrodeposition
ITO
Raman spectroscopy
Sodium nitrate

Access to Document

10.1109/INEC.2008.4585593

Cite this

@inproceedings{8aeff1accea14d488970aad82b13537d,

title = "Electrochemic growth of CuInSe2 thin film on ITO/soda-lime glass from acidic medium",

abstract = "The simultaneous electrodeposition of the Cu-In-Se system was investigated. The study was carried out at pH 1.8 using Sodium citrate as completing agent for the Cu2+ ion. The synthesis of CuInSe2 semiconductor thin film was carried out by electrodeposition on indium-tin oxide (ITO) /soda-lime glass. The simultaneous codeposition of the Cu, In, and Se was achieved by constant potential electrolysis technique in aqueous solutions containing CuCl2, InCl3, and H2SeO3. The as-deposited and annealed films were characterized by scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy (EDX), x-ray diffraction (XRD), and Raman spectroscopy. Homogeneous films were deposited with a well-defined composition and chalcopyrite structure. The crystallinity of the films was improved by annealing. The deposited stoichiometric CuInSe2 layers were about 2 μm in thickness. The annealed film is with a perfect crystallized and single chalcopyrite structure. It is suitable for photovoltaic applications.",

keywords = "Chalcopyrite, CuInSe (CIS), Electrodeposition, ITO, Raman spectroscopy, Sodium nitrate",

author = "Yao, \{N. J.\} and Huang, \{S. M.\} and Pan, \{L. K.\} and Z. Sun and Chen, \{Y. W.\}",

year = "2008",

doi = "10.1109/INEC.2008.4585593",

language = "英语",

isbn = "9781424415731",

series = "2008 2nd IEEE International Nanoelectronics Conference, INEC 2008",

pages = "751--754",

booktitle = "2008 2nd IEEE International Nanoelectronics Conference, INEC 2008",

note = "2008 2nd IEEE International Nanoelectronics Conference, INEC 2008 ; Conference date: 24-03-2008 Through 27-03-2008",

}

Yao, NJ, Huang, SM, Pan, LK , Sun, Z & Chen, YW 2008, Electrochemic growth of CuInSe₂ thin film on ITO/soda-lime glass from acidic medium. in 2008 2nd IEEE International Nanoelectronics Conference, INEC 2008., 4585593, 2008 2nd IEEE International Nanoelectronics Conference, INEC 2008, pp. 751-754, 2008 2nd IEEE International Nanoelectronics Conference, INEC 2008, Shanghai, China, 24/03/08. https://doi.org/10.1109/INEC.2008.4585593

Electrochemic growth of CuInSe₂ thin film on ITO/soda-lime glass from acidic medium. / Yao, N. J.; Huang, S. M.; Pan, L. K. et al.
2008 2nd IEEE International Nanoelectronics Conference, INEC 2008. 2008. p. 751-754 4585593 (2008 2nd IEEE International Nanoelectronics Conference, INEC 2008).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Electrochemic growth of CuInSe2 thin film on ITO/soda-lime glass from acidic medium

AU - Yao, N. J.

AU - Huang, S. M.

AU - Pan, L. K.

AU - Sun, Z.

AU - Chen, Y. W.

PY - 2008

Y1 - 2008

N2 - The simultaneous electrodeposition of the Cu-In-Se system was investigated. The study was carried out at pH 1.8 using Sodium citrate as completing agent for the Cu2+ ion. The synthesis of CuInSe2 semiconductor thin film was carried out by electrodeposition on indium-tin oxide (ITO) /soda-lime glass. The simultaneous codeposition of the Cu, In, and Se was achieved by constant potential electrolysis technique in aqueous solutions containing CuCl2, InCl3, and H2SeO3. The as-deposited and annealed films were characterized by scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy (EDX), x-ray diffraction (XRD), and Raman spectroscopy. Homogeneous films were deposited with a well-defined composition and chalcopyrite structure. The crystallinity of the films was improved by annealing. The deposited stoichiometric CuInSe2 layers were about 2 μm in thickness. The annealed film is with a perfect crystallized and single chalcopyrite structure. It is suitable for photovoltaic applications.

AB - The simultaneous electrodeposition of the Cu-In-Se system was investigated. The study was carried out at pH 1.8 using Sodium citrate as completing agent for the Cu2+ ion. The synthesis of CuInSe2 semiconductor thin film was carried out by electrodeposition on indium-tin oxide (ITO) /soda-lime glass. The simultaneous codeposition of the Cu, In, and Se was achieved by constant potential electrolysis technique in aqueous solutions containing CuCl2, InCl3, and H2SeO3. The as-deposited and annealed films were characterized by scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy (EDX), x-ray diffraction (XRD), and Raman spectroscopy. Homogeneous films were deposited with a well-defined composition and chalcopyrite structure. The crystallinity of the films was improved by annealing. The deposited stoichiometric CuInSe2 layers were about 2 μm in thickness. The annealed film is with a perfect crystallized and single chalcopyrite structure. It is suitable for photovoltaic applications.

KW - Chalcopyrite

KW - CuInSe (CIS)

KW - Electrodeposition

KW - ITO

KW - Raman spectroscopy

KW - Sodium nitrate

UR - https://www.scopus.com/pages/publications/52649141666

U2 - 10.1109/INEC.2008.4585593

DO - 10.1109/INEC.2008.4585593

M3 - 会议稿件

AN - SCOPUS:52649141666

SN - 9781424415731

T3 - 2008 2nd IEEE International Nanoelectronics Conference, INEC 2008

SP - 751

EP - 754

BT - 2008 2nd IEEE International Nanoelectronics Conference, INEC 2008

T2 - 2008 2nd IEEE International Nanoelectronics Conference, INEC 2008

Y2 - 24 March 2008 through 27 March 2008

ER -