TY - JOUR
T1 - Electrocatalytic hydrogenation of biomass-derived organics
T2 - A review
AU - Akhade, Sneha A.
AU - Singh, Nirala
AU - Gutierrez, Oliver Y.
AU - Lopez-Ruiz, Juan
AU - Wang, Huamin
AU - Holladay, Jamie D.
AU - Liu, Yue
AU - Karkamkar, Abhijeet
AU - Weber, Robert S.
AU - Padmaperuma, Asanga B.
AU - Lee, Mal Soon
AU - Whyatt, Greg A.
AU - Elliott, Michael
AU - Holladay, Johnathan E.
AU - Male, Jonathan L.
AU - Lercher, Johannes A.
AU - Rousseau, Roger
AU - Glezakou, Vassiliki Alexandra
N1 - Publisher Copyright:
© 2020 American Chemical Society
PY - 2020/10/28
Y1 - 2020/10/28
N2 - Sustainable energy generation calls for a shift away from centralized, high-temperature, energy-intensive processes to decentralized, low-temperature conversions that can be powered by electricity produced from renewable sources. Electrocatalytic conversion of biomass-derived feedstocks would allow carbon recycling of distributed, energy-poor resources in the absence of sinks and sources of high-grade heat. Selective, efficient electrocatalysts that operate at low temperatures are needed for electrocatalytic hydrogenation (ECH) to upgrade the feedstocks. For effective generation of energy-dense chemicals and fuels, two design criteria must be met: (i) a high H:C ratio via ECH to allow for high-quality fuels and blends and (ii) a lower O:C ratio in the target molecules via electrochemical decarboxylation/ deoxygenation to improve the stability of fuels and chemicals.
AB - Sustainable energy generation calls for a shift away from centralized, high-temperature, energy-intensive processes to decentralized, low-temperature conversions that can be powered by electricity produced from renewable sources. Electrocatalytic conversion of biomass-derived feedstocks would allow carbon recycling of distributed, energy-poor resources in the absence of sinks and sources of high-grade heat. Selective, efficient electrocatalysts that operate at low temperatures are needed for electrocatalytic hydrogenation (ECH) to upgrade the feedstocks. For effective generation of energy-dense chemicals and fuels, two design criteria must be met: (i) a high H:C ratio via ECH to allow for high-quality fuels and blends and (ii) a lower O:C ratio in the target molecules via electrochemical decarboxylation/ deoxygenation to improve the stability of fuels and chemicals.
UR - https://www.scopus.com/pages/publications/85092585557
U2 - 10.1021/acs.chemrev.0c00158
DO - 10.1021/acs.chemrev.0c00158
M3 - 文献综述
C2 - 32941005
AN - SCOPUS:85092585557
SN - 0009-2665
VL - 120
SP - 11370
EP - 11419
JO - Chemical Reviews
JF - Chemical Reviews
IS - 20
ER -
