Electrocatalytic asymmetric reduction of ethyl benzoylformate on bimetallic Ag–Cu cathodes

Shuo Wang; Yi Shi; Yue Hou; Si Li Shan; Huan Wang; Jia Xing Lu

doi:10.1007/s10800-020-01449-6

Electrocatalytic asymmetric reduction of ethyl benzoylformate on bimetallic Ag–Cu cathodes

Shuo Wang
, Yi Shi
, Yue Hou
, Si Li Shan
, Huan Wang^*
, Jia Xing Lu^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Abstract: Ag–Cu bimetallic nanoparticles were synthesised and used as cathode materials for the asymmetric electroreduction of ethyl benzoylformate. The reaction induced by cinchonidine was conducted in an undivided cell to produce the optically active ethyl mandelate. We obtained ethyl mandelate with 54% enantiomeric excess and 42% yield under the optimal conditions. Graphic abstract: [Figure not available: see fulltext.]

Original language	English
Pages (from-to)	973-978
Number of pages	6
Journal	Journal of Applied Electrochemistry
Volume	50
Issue number	9
DOIs	https://doi.org/10.1007/s10800-020-01449-6
State	Published - 1 Sep 2020

Keywords

Ag–Cu NPs
Asymmetric electroreduction
Cinchonidine
Ethyl benzoylformate
Ethyl mandelate

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10.1007/s10800-020-01449-6

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@article{3925c5b3f6f34d15b2afd52a60119470,

title = "Electrocatalytic asymmetric reduction of ethyl benzoylformate on bimetallic Ag–Cu cathodes",

abstract = "Abstract: Ag–Cu bimetallic nanoparticles were synthesised and used as cathode materials for the asymmetric electroreduction of ethyl benzoylformate. The reaction induced by cinchonidine was conducted in an undivided cell to produce the optically active ethyl mandelate. We obtained ethyl mandelate with 54\% enantiomeric excess and 42\% yield under the optimal conditions. Graphic abstract: [Figure not available: see fulltext.]",

keywords = "Ag–Cu NPs, Asymmetric electroreduction, Cinchonidine, Ethyl benzoylformate, Ethyl mandelate",

author = "Shuo Wang and Yi Shi and Yue Hou and Shan, \{Si Li\} and Huan Wang and Lu, \{Jia Xing\}",

note = "Publisher Copyright: {\textcopyright} 2020, Springer Nature B.V.",

year = "2020",

month = sep,

day = "1",

doi = "10.1007/s10800-020-01449-6",

language = "英语",

volume = "50",

pages = "973--978",

journal = "Journal of Applied Electrochemistry",

issn = "0021-891X",

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TY - JOUR

T1 - Electrocatalytic asymmetric reduction of ethyl benzoylformate on bimetallic Ag–Cu cathodes

AU - Wang, Shuo

AU - Shi, Yi

AU - Hou, Yue

AU - Shan, Si Li

AU - Wang, Huan

AU - Lu, Jia Xing

PY - 2020/9/1

Y1 - 2020/9/1

N2 - Abstract: Ag–Cu bimetallic nanoparticles were synthesised and used as cathode materials for the asymmetric electroreduction of ethyl benzoylformate. The reaction induced by cinchonidine was conducted in an undivided cell to produce the optically active ethyl mandelate. We obtained ethyl mandelate with 54% enantiomeric excess and 42% yield under the optimal conditions. Graphic abstract: [Figure not available: see fulltext.]

AB - Abstract: Ag–Cu bimetallic nanoparticles were synthesised and used as cathode materials for the asymmetric electroreduction of ethyl benzoylformate. The reaction induced by cinchonidine was conducted in an undivided cell to produce the optically active ethyl mandelate. We obtained ethyl mandelate with 54% enantiomeric excess and 42% yield under the optimal conditions. Graphic abstract: [Figure not available: see fulltext.]

KW - Ag–Cu NPs

KW - Asymmetric electroreduction

KW - Cinchonidine

KW - Ethyl benzoylformate

KW - Ethyl mandelate

UR - https://www.scopus.com/pages/publications/85087694585

U2 - 10.1007/s10800-020-01449-6

DO - 10.1007/s10800-020-01449-6

M3 - 文章

AN - SCOPUS:85087694585

SN - 0021-891X

VL - 50

SP - 973

EP - 978

JO - Journal of Applied Electrochemistry

JF - Journal of Applied Electrochemistry

IS - 9

ER -

Electrocatalytic asymmetric reduction of ethyl benzoylformate on bimetallic Ag–Cu cathodes

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Keywords

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