TY - JOUR
T1 - Eight-position substitution effects on laser action of the 1,3,5,7-tetramethyl-2,6-diethyl pyrromethene-BF2 complexes
AU - Liang, Feng
AU - Zeng, Heping
AU - Sun, Zhenrong
AU - Yuan, Yizhong
AU - Yao, Zuguang
AU - Xu, Zhizhan
PY - 2001/12
Y1 - 2001/12
N2 - We measured laser-action properties of some novel eight-position substituted 1,3,5,7-tetramethyl-2,6-diethyl pyrromethene-BF2 complexes in a Littman-type cavity pumped by the second harmonic of a Q-switched Nd:YAG laser. The substitution effects were investigated by comparing the spectroscopic and laser-action properties of various eight-position substituted complexes, such as absorption, excitation, and fluorescence emission, and triplet-triplet absorption spectra, dye-laser wavelength-tuning spectra, and output-pulse energy versus the pump-laser energy. The results showed that 1,3,5,7-tetramethyl-2,6-diethyl pyrromethene-BF 2 complexes with phenyl, p-methoxyphenyl, and p-fluorophenyl substituted at the eight-position outperformed the commercially available benchmark laser dye Rhodamine 6G (Rh6G) in fluorescence quantum yields, laser efficiency, and laser wavelength-tuning range.
AB - We measured laser-action properties of some novel eight-position substituted 1,3,5,7-tetramethyl-2,6-diethyl pyrromethene-BF2 complexes in a Littman-type cavity pumped by the second harmonic of a Q-switched Nd:YAG laser. The substitution effects were investigated by comparing the spectroscopic and laser-action properties of various eight-position substituted complexes, such as absorption, excitation, and fluorescence emission, and triplet-triplet absorption spectra, dye-laser wavelength-tuning spectra, and output-pulse energy versus the pump-laser energy. The results showed that 1,3,5,7-tetramethyl-2,6-diethyl pyrromethene-BF 2 complexes with phenyl, p-methoxyphenyl, and p-fluorophenyl substituted at the eight-position outperformed the commercially available benchmark laser dye Rhodamine 6G (Rh6G) in fluorescence quantum yields, laser efficiency, and laser wavelength-tuning range.
UR - https://www.scopus.com/pages/publications/0001603043
U2 - 10.1364/JOSAB.18.001841
DO - 10.1364/JOSAB.18.001841
M3 - 文章
AN - SCOPUS:0001603043
SN - 0740-3224
VL - 18
SP - 1841
EP - 1845
JO - Journal of the Optical Society of America B: Optical Physics
JF - Journal of the Optical Society of America B: Optical Physics
IS - 12
ER -