Efficient conversion of furfural to furfural amine over 4Ru1Co/AC catalyst

Gou Le Gou; Longfei Xie; Yuanyuan Wang; Liyi Dai

doi:10.1016/j.apcata.2022.118902

Efficient conversion of furfural to furfural amine over 4Ru1Co/AC catalyst

Gou Le Gou
, Longfei Xie
, Yuanyuan Wang^*
, Liyi Dai

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University
Institute of Eco-Chongming

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The production of amine intermediates from biomass is capturing increasing attention. Herein, an efficient conversion of furfural to furfural amine over RuCo/AC catalyst under hydrothermal conditions has been investigated. The effects of different carriers, bimetals, and reaction conditions were systematically investigated in green solvents (water). Fully conversion of furfural and high furfural amine yield (92.13%) at 80 ℃ for 1 h over 4Ru1Co/AC. The excellent catalytic performance of 4Ru1Co/AC was attributed to its high acidity and good hydrogenation ability, as well as the synergistic effect between Ru-Co alloy formations and the activated carbon. Importantly, the highly selective preparation of furfural to furfural amine is a promising way to high-value utilization of cellulosic biomass in green solvents.

Original language	English
Article number	118902
Journal	Applied Catalysis A: General
Volume	647
DOIs	https://doi.org/10.1016/j.apcata.2022.118902
State	Published - 25 Oct 2022

Keywords

Activated carbon
Bimetal
Catalytic amination
Furfural amine

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10.1016/j.apcata.2022.118902

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title = "Efficient conversion of furfural to furfural amine over 4Ru1Co/AC catalyst",

abstract = "The production of amine intermediates from biomass is capturing increasing attention. Herein, an efficient conversion of furfural to furfural amine over RuCo/AC catalyst under hydrothermal conditions has been investigated. The effects of different carriers, bimetals, and reaction conditions were systematically investigated in green solvents (water). Fully conversion of furfural and high furfural amine yield (92.13\%) at 80 ℃ for 1 h over 4Ru1Co/AC. The excellent catalytic performance of 4Ru1Co/AC was attributed to its high acidity and good hydrogenation ability, as well as the synergistic effect between Ru-Co alloy formations and the activated carbon. Importantly, the highly selective preparation of furfural to furfural amine is a promising way to high-value utilization of cellulosic biomass in green solvents.",

keywords = "Activated carbon, Bimetal, Catalytic amination, Furfural amine",

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year = "2022",

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doi = "10.1016/j.apcata.2022.118902",

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T1 - Efficient conversion of furfural to furfural amine over 4Ru1Co/AC catalyst

AU - Le Gou, Gou

AU - Xie, Longfei

AU - Wang, Yuanyuan

AU - Dai, Liyi

PY - 2022/10/25

Y1 - 2022/10/25

N2 - The production of amine intermediates from biomass is capturing increasing attention. Herein, an efficient conversion of furfural to furfural amine over RuCo/AC catalyst under hydrothermal conditions has been investigated. The effects of different carriers, bimetals, and reaction conditions were systematically investigated in green solvents (water). Fully conversion of furfural and high furfural amine yield (92.13%) at 80 ℃ for 1 h over 4Ru1Co/AC. The excellent catalytic performance of 4Ru1Co/AC was attributed to its high acidity and good hydrogenation ability, as well as the synergistic effect between Ru-Co alloy formations and the activated carbon. Importantly, the highly selective preparation of furfural to furfural amine is a promising way to high-value utilization of cellulosic biomass in green solvents.

AB - The production of amine intermediates from biomass is capturing increasing attention. Herein, an efficient conversion of furfural to furfural amine over RuCo/AC catalyst under hydrothermal conditions has been investigated. The effects of different carriers, bimetals, and reaction conditions were systematically investigated in green solvents (water). Fully conversion of furfural and high furfural amine yield (92.13%) at 80 ℃ for 1 h over 4Ru1Co/AC. The excellent catalytic performance of 4Ru1Co/AC was attributed to its high acidity and good hydrogenation ability, as well as the synergistic effect between Ru-Co alloy formations and the activated carbon. Importantly, the highly selective preparation of furfural to furfural amine is a promising way to high-value utilization of cellulosic biomass in green solvents.

KW - Activated carbon

KW - Bimetal

KW - Catalytic amination

KW - Furfural amine

UR - https://www.scopus.com/pages/publications/85139856526

U2 - 10.1016/j.apcata.2022.118902

DO - 10.1016/j.apcata.2022.118902

M3 - 文章

AN - SCOPUS:85139856526

SN - 0926-860X

VL - 647

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

M1 - 118902

ER -

Efficient conversion of furfural to furfural amine over 4Ru1Co/AC catalyst

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Keywords

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