Efficient catalytic enantioselective Nazarov cyclizations of divinyl ketoesters

Zhou Xu; Hai Ren; Lijia Wang; Yong Tang

doi:10.1039/c5qo00099h

Efficient catalytic enantioselective Nazarov cyclizations of divinyl ketoesters

Zhou Xu
, Hai Ren
, Lijia Wang^*
, Yong Tang

^*Corresponding author for this work

CAS - Shanghai Institute of Organic Chemistry
Xuzhou Medical University

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

An efficient catalytic enantioselective Nazarov cyclization of divinyl ketoesters was developed using a chiral BOX/Cu(ii) complex, which provides facile access to a variety of optically active multi-substituted cyclopent-2-enone esters in 78-95% yields with 78-90% ee.

Original language	English
Pages (from-to)	811-814
Number of pages	4
Journal	Organic Chemistry Frontiers
Volume	2
Issue number	7
DOIs	https://doi.org/10.1039/c5qo00099h
State	Published - Jul 2015
Externally published	Yes

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title = "Efficient catalytic enantioselective Nazarov cyclizations of divinyl ketoesters",

abstract = "An efficient catalytic enantioselective Nazarov cyclization of divinyl ketoesters was developed using a chiral BOX/Cu(ii) complex, which provides facile access to a variety of optically active multi-substituted cyclopent-2-enone esters in 78-95\% yields with 78-90\% ee.",

author = "Zhou Xu and Hai Ren and Lijia Wang and Yong Tang",

note = "Publisher Copyright: {\textcopyright} 2015 the Partner Organisations.",

year = "2015",

month = jul,

doi = "10.1039/c5qo00099h",

language = "英语",

volume = "2",

pages = "811--814",

journal = "Organic Chemistry Frontiers",

issn = "2052-4110",

publisher = "Royal Society of Chemistry",

number = "7",

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TY - JOUR

T1 - Efficient catalytic enantioselective Nazarov cyclizations of divinyl ketoesters

AU - Xu, Zhou

AU - Ren, Hai

AU - Wang, Lijia

AU - Tang, Yong

PY - 2015/7

Y1 - 2015/7

N2 - An efficient catalytic enantioselective Nazarov cyclization of divinyl ketoesters was developed using a chiral BOX/Cu(ii) complex, which provides facile access to a variety of optically active multi-substituted cyclopent-2-enone esters in 78-95% yields with 78-90% ee.

AB - An efficient catalytic enantioselective Nazarov cyclization of divinyl ketoesters was developed using a chiral BOX/Cu(ii) complex, which provides facile access to a variety of optically active multi-substituted cyclopent-2-enone esters in 78-95% yields with 78-90% ee.

UR - https://www.scopus.com/pages/publications/84942942749

U2 - 10.1039/c5qo00099h

DO - 10.1039/c5qo00099h

M3 - 文章

AN - SCOPUS:84942942749

SN - 2052-4110

VL - 2

SP - 811

EP - 814

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 7

ER -

Efficient catalytic enantioselective Nazarov cyclizations of divinyl ketoesters

Abstract

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