Efficient Baylis-Hillman reaction via a 1,4-diazabicyclo[2.2.2]octane-based ionic catalyst

Yueqin Cai; Ye Liu; Guohua Gao

doi:10.1007/s00706-007-0693-3

Efficient Baylis-Hillman reaction via a 1,4-diazabicyclo[2.2.2]octane-based ionic catalyst

Yueqin Cai, Ye Liu, Guohua Gao

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A novel ionic catalyst, 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride based on 1,4-diazabicyclo[2.2.2]octane was synthesized and applied in the Baylis-Hillman reaction, which occurred readily at room temperature to afford the corresponding adducts in good yield. The ionic catalyst could be recycled for seven runs without diminution in its catalytic activity.

Original language	English
Pages (from-to)	1163-1166
Number of pages	4
Journal	Monatshefte fur Chemie
Volume	138
Issue number	11
DOIs	https://doi.org/10.1007/s00706-007-0693-3
State	Published - Nov 2007

Keywords

Acrylates
Aldehydes
Baylis-Hillman reaction
Catalysts
Homogeneous catalysis

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10.1007/s00706-007-0693-3

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title = "Efficient Baylis-Hillman reaction via a 1,4-diazabicyclo[2.2.2]octane-based ionic catalyst",

abstract = "A novel ionic catalyst, 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride based on 1,4-diazabicyclo[2.2.2]octane was synthesized and applied in the Baylis-Hillman reaction, which occurred readily at room temperature to afford the corresponding adducts in good yield. The ionic catalyst could be recycled for seven runs without diminution in its catalytic activity.",

keywords = "Acrylates, Aldehydes, Baylis-Hillman reaction, Catalysts, Homogeneous catalysis",

author = "Yueqin Cai and Ye Liu and Guohua Gao",

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AU - Cai, Yueqin

AU - Liu, Ye

AU - Gao, Guohua

PY - 2007/11

Y1 - 2007/11

N2 - A novel ionic catalyst, 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride based on 1,4-diazabicyclo[2.2.2]octane was synthesized and applied in the Baylis-Hillman reaction, which occurred readily at room temperature to afford the corresponding adducts in good yield. The ionic catalyst could be recycled for seven runs without diminution in its catalytic activity.

AB - A novel ionic catalyst, 1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride based on 1,4-diazabicyclo[2.2.2]octane was synthesized and applied in the Baylis-Hillman reaction, which occurred readily at room temperature to afford the corresponding adducts in good yield. The ionic catalyst could be recycled for seven runs without diminution in its catalytic activity.

KW - Acrylates

KW - Aldehydes

KW - Baylis-Hillman reaction

KW - Catalysts

KW - Homogeneous catalysis

UR - https://www.scopus.com/pages/publications/35648941288

U2 - 10.1007/s00706-007-0693-3

DO - 10.1007/s00706-007-0693-3

M3 - 文章

AN - SCOPUS:35648941288

SN - 0026-9247

VL - 138

SP - 1163

EP - 1166

JO - Monatshefte fur Chemie

JF - Monatshefte fur Chemie

IS - 11

ER -

Efficient Baylis-Hillman reaction via a 1,4-diazabicyclo[2.2.2]octane-based ionic catalyst

Abstract

Keywords

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