Effective and reusable Pt catalysts supported on periodic mesoporous resols for chiral hydrogenation

Xiaohong Li; Yali Shen; Rong Xing; Yueming Liu; Haihong Wu; Mingyuan He; Peng Wu

doi:10.1007/s10562-007-9381-5

Effective and reusable Pt catalysts supported on periodic mesoporous resols for chiral hydrogenation

Xiaohong Li^*
, Yali Shen
, Rong Xing
, Yueming Liu
, Haihong Wu
, Mingyuan He
, Peng Wu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Platinum nanoparticles supported on periodic mesoporous resols by simple impregnation serve as effective, robust and remarkably reusable catalysts after chirally modified with cinchonidine for the asymmetric hydrogenation of ethyl pyruvate, affording up to 62% enantiomeric excess (ee) and a constant activity after 25th re-use. They can also catalyze the reaction in an environmentally benign manner by using water as a solvent.

Original language	English
Pages (from-to)	325-329
Number of pages	5
Journal	Catalysis Letters
Volume	122
Issue number	3-4
DOIs	https://doi.org/10.1007/s10562-007-9381-5
State	Published - May 2008

Keywords

Enantioselective hydrogenation
Ethyl pyruvate
Periodic mesoporous resols
Pt/FDU-15

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10.1007/s10562-007-9381-5

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title = "Effective and reusable Pt catalysts supported on periodic mesoporous resols for chiral hydrogenation",

abstract = "Platinum nanoparticles supported on periodic mesoporous resols by simple impregnation serve as effective, robust and remarkably reusable catalysts after chirally modified with cinchonidine for the asymmetric hydrogenation of ethyl pyruvate, affording up to 62\% enantiomeric excess (ee) and a constant activity after 25th re-use. They can also catalyze the reaction in an environmentally benign manner by using water as a solvent.",

keywords = "Enantioselective hydrogenation, Ethyl pyruvate, Periodic mesoporous resols, Pt/FDU-15",

author = "Xiaohong Li and Yali Shen and Rong Xing and Yueming Liu and Haihong Wu and Mingyuan He and Peng Wu",

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T1 - Effective and reusable Pt catalysts supported on periodic mesoporous resols for chiral hydrogenation

AU - Li, Xiaohong

AU - Shen, Yali

AU - Xing, Rong

AU - Liu, Yueming

AU - Wu, Haihong

AU - He, Mingyuan

AU - Wu, Peng

PY - 2008/5

Y1 - 2008/5

N2 - Platinum nanoparticles supported on periodic mesoporous resols by simple impregnation serve as effective, robust and remarkably reusable catalysts after chirally modified with cinchonidine for the asymmetric hydrogenation of ethyl pyruvate, affording up to 62% enantiomeric excess (ee) and a constant activity after 25th re-use. They can also catalyze the reaction in an environmentally benign manner by using water as a solvent.

AB - Platinum nanoparticles supported on periodic mesoporous resols by simple impregnation serve as effective, robust and remarkably reusable catalysts after chirally modified with cinchonidine for the asymmetric hydrogenation of ethyl pyruvate, affording up to 62% enantiomeric excess (ee) and a constant activity after 25th re-use. They can also catalyze the reaction in an environmentally benign manner by using water as a solvent.

KW - Enantioselective hydrogenation

KW - Ethyl pyruvate

KW - Periodic mesoporous resols

KW - Pt/FDU-15

UR - https://www.scopus.com/pages/publications/43049155990

U2 - 10.1007/s10562-007-9381-5

DO - 10.1007/s10562-007-9381-5

M3 - 文章

AN - SCOPUS:43049155990

SN - 1011-372X

VL - 122

SP - 325

EP - 329

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3-4

ER -

Effective and reusable Pt catalysts supported on periodic mesoporous resols for chiral hydrogenation

Abstract

Keywords

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