Effect of top electrodes on photovoltaic properties of polycrystalline BiFeO3 based thin film capacitors

Bin Chen, Mi Li, Yiwei Liu, Zhenghu Zuo, Fei Zhuge, Qing Feng Zhan, Run Wei Li

Research output: Contribution to journalArticlepeer-review

175 Scopus citations

Abstract

We investigated capacitors based on polycrystalline narrow-band-gap BiFeO3 (BFO) thin films with different top electrodes. The photovoltaic response for the capacitor with a Sn-doped In2O 3 (ITO) top electrode is about 25 times higher than that with a Au top electrode, which indicates that the electrode plays a key role in determining the photovoltaic response of ferroelectric thin film capacitors, as simulated by Qin et al (2009 Appl. Phys. Lett. 95 22912). The light-to-electricity photovoltaic efficiency for the ITO/polycrystalline BFO/Pt capacitor can reach 0.125%. Furthermore, under incident light of 450νWcm -2 and zero bias, the corresponding photocurrent varies from 0.2 to 200pA, that is, almost a 1000-fold photoconductivity enhancement. Our experiments suggest that polycrystalline BFO films are promising materials for application in photo-sensitive and energy-related devices.

Original languageEnglish
Article number195201
JournalNanotechnology
Volume22
Issue number19
DOIs
StatePublished - 13 May 2011
Externally publishedYes

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