Effect of sulfate radical oxidation on disintegration of waste activated sludge

Weichao Ren, Zhen Zhou*, Yeye Zhu, Lu Man Jiang, Haijuan Wei, Tianhao Niu, Penghao Fu, Zhan Qiu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

72 Scopus citations

Abstract

The effects of sulfate radical oxidation pretreatment on the disintegration of waste activated sludge were investigated at different dosages of peroxymonosulfate (PMS). Indicators for estimating sludge disintegration were selected by analyzing concentrations of released substances and statistical analysis. Results indicated that COD and total phosphorus (TP) were unsuitable for estimating sludge disintegration by oxidants. Pearson correlation analysis indicated that total nitrogen (TN), total organic carbon (TOC), UV254 and polysaccharides had strong correlation with each other, thus suitable for sludge disintegration estimation. Chemical analysis and 3D-EEM fluorescence spectra showed that at high dosage, sulfate radical oxidation was effective for sludge disintegration by inducing aromatic and tryptophan protein-like substances degradation. At PMS dosage of 12mg(g SS)-1, sludge disintegration degrees in TOC and TN were 24.8% and 29.9%, respectively.

Original languageEnglish
Pages (from-to)384-390
Number of pages7
JournalInternational Biodeterioration and Biodegradation
Volume104
DOIs
StatePublished - 1 Oct 2015
Externally publishedYes

Keywords

  • Dissolved organic matters (DOM)
  • Excitation-emission matrix (EEM)
  • Sludge disintegration
  • Sulfate radicals
  • Waste activated sludge

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