Abstract
ECNU-10, an analogue of MCM-49 with the 3-dimensional (3D) MWW topology, was synthesized using 1-adamantanamine as structure directing agent (SDA), which is the second example of 3D MWW zeolite obtained by direct hydrothermal synthesis. The synthesis condition was investigated and proton-type ECNU-10 showed similar Al distribution with conventional MCM-22 obtained by the interlayer condensation of a layer precursor, as revealed by 27Al 3Q MAS NMR analysis. The catalytic performance of ECNU-10 was evaluated in the alkylation and disproportionation reactions in comparison to another two MWW-type aluminosilicates of MCM-22 and SSZ-25.
| Original language | English |
|---|---|
| Pages (from-to) | 137-145 |
| Number of pages | 9 |
| Journal | Microporous and Mesoporous Materials |
| Volume | 253 |
| DOIs | |
| State | Published - 2017 |
Keywords
- 1-Adamantanamine
- Alkylation
- Aluminosilicate
- Disproportionation
- MWW zeolite