Abstract
The dissociative double ionization and multi-photon ionization of 1-bromo-2-chloroethane (BCE) irradiated by the 800 nm femtosecond laser field have been investigated by dc-slice imaging technology. The charged parent ion ratio BCE2BCE was measured, and the corresponding ionization process including non-sequential double ionization and sequential double ionization was analyzed. The sliced images of different photo-dissociated ions were detected, and the corresponding kinetic energy release (KER) distributions were calculated and extracted. Furthermore, the dissociative double ionization channels, attributed to the cleavage of the C-C, C-Br, and C-Cl bonds by the Coulombic repulsive forces, were discussed, and the revised equilibrium distance R e *, the energy ratio EexpEcoul, and the value a=Re*(Eexp/Ecoul) were calculated.
| Original language | English |
|---|---|
| Article number | 064303 |
| Journal | Journal of Chemical Physics |
| Volume | 135 |
| Issue number | 6 |
| DOIs | |
| State | Published - 14 Aug 2011 |
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