Dissociative double ionization of 1-bromo-2-chloroethane irradiated by an intense femtosecond laser field

  • Yan Yang
  • , Lulu Fan
  • , Shengzhi Sun
  • , Jian Zhang
  • , Yuting Chen
  • , Shian Zhang
  • , Tianqing Jia
  • , Zhenrong Sun*
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

The dissociative double ionization and multi-photon ionization of 1-bromo-2-chloroethane (BCE) irradiated by the 800 nm femtosecond laser field have been investigated by dc-slice imaging technology. The charged parent ion ratio BCE2BCE was measured, and the corresponding ionization process including non-sequential double ionization and sequential double ionization was analyzed. The sliced images of different photo-dissociated ions were detected, and the corresponding kinetic energy release (KER) distributions were calculated and extracted. Furthermore, the dissociative double ionization channels, attributed to the cleavage of the C-C, C-Br, and C-Cl bonds by the Coulombic repulsive forces, were discussed, and the revised equilibrium distance R e *, the energy ratio EexpEcoul, and the value a=Re*(Eexp/Ecoul) were calculated.

Original languageEnglish
Article number064303
JournalJournal of Chemical Physics
Volume135
Issue number6
DOIs
StatePublished - 14 Aug 2011

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