Direct Self-Assembly of a 2D and 3D Star of David

Bo Song; Zhe Zhang; Kun Wang; Chih Hao Hsu; Olapeju Bolarinwa; Jing Wang; Yiming Li; Guang Qiang Yin; Edwin Rivera; Hai Bo Yang; Changlin Liu; Bingqian Xu; Xiaopeng Li

doi:10.1002/anie.201701417

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

University of South Florida
Central China Normal University
University of Georgia
University of Akron
East China Normal University

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Two- and three-dimensional metallosupramolecules shaped like a Star of David were synthesized by the self-assembly of a tetratopic pyridyl ligand with a 180° diplatinum(II) motif and Pd^II ions, respectively. In contrast to other strategies, such as template-directed synthesis and stepwise self-assembly, this design enables the formation of 2D and 3D structures in one step and high yield. The structures were characterized by both one-dimensional (¹H, ¹³C, ³¹P) and two-dimensional (COSY, NOESY, DOSY) NMR spectroscopy, ESI-MS, ion-mobility mass spectrometry (IM–MS), AFM, and TEM. The stabilities of the 2D and 3D structures were measured and compared by gradient tandem mass spectrometry (gMS²). The high stability of the 3D Star of David was correlated to its high density of coordination sites (DOCS).

Original language	English
Pages (from-to)	5258-5262
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	56
Issue number	19
DOIs	https://doi.org/10.1002/anie.201701417
State	Published - 2 May 2017

Keywords

ion-mobility mass spectrometry
metallosupramolecules
multitopic ligands
self-assembly
supramolecular chemistry

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10.1002/anie.201701417

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title = "Direct Self-Assembly of a 2D and 3D Star of David",

abstract = "Two- and three-dimensional metallosupramolecules shaped like a Star of David were synthesized by the self-assembly of a tetratopic pyridyl ligand with a 180° diplatinum(II) motif and PdII ions, respectively. In contrast to other strategies, such as template-directed synthesis and stepwise self-assembly, this design enables the formation of 2D and 3D structures in one step and high yield. The structures were characterized by both one-dimensional (1H, 13C, 31P) and two-dimensional (COSY, NOESY, DOSY) NMR spectroscopy, ESI-MS, ion-mobility mass spectrometry (IM–MS), AFM, and TEM. The stabilities of the 2D and 3D structures were measured and compared by gradient tandem mass spectrometry (gMS2). The high stability of the 3D Star of David was correlated to its high density of coordination sites (DOCS).",

keywords = "ion-mobility mass spectrometry, metallosupramolecules, multitopic ligands, self-assembly, supramolecular chemistry",

author = "Bo Song and Zhe Zhang and Kun Wang and Hsu, \{Chih Hao\} and Olapeju Bolarinwa and Jing Wang and Yiming Li and Yin, \{Guang Qiang\} and Edwin Rivera and Yang, \{Hai Bo\} and Changlin Liu and Bingqian Xu and Xiaopeng Li",

note = "Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2017",

month = may,

day = "2",

doi = "10.1002/anie.201701417",

language = "英语",

volume = "56",

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journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Direct Self-Assembly of a 2D and 3D Star of David

AU - Song, Bo

AU - Zhang, Zhe

AU - Wang, Kun

AU - Hsu, Chih Hao

AU - Bolarinwa, Olapeju

AU - Wang, Jing

AU - Li, Yiming

AU - Yin, Guang Qiang

AU - Rivera, Edwin

AU - Yang, Hai Bo

AU - Liu, Changlin

AU - Xu, Bingqian

AU - Li, Xiaopeng

PY - 2017/5/2

Y1 - 2017/5/2

N2 - Two- and three-dimensional metallosupramolecules shaped like a Star of David were synthesized by the self-assembly of a tetratopic pyridyl ligand with a 180° diplatinum(II) motif and PdII ions, respectively. In contrast to other strategies, such as template-directed synthesis and stepwise self-assembly, this design enables the formation of 2D and 3D structures in one step and high yield. The structures were characterized by both one-dimensional (1H, 13C, 31P) and two-dimensional (COSY, NOESY, DOSY) NMR spectroscopy, ESI-MS, ion-mobility mass spectrometry (IM–MS), AFM, and TEM. The stabilities of the 2D and 3D structures were measured and compared by gradient tandem mass spectrometry (gMS2). The high stability of the 3D Star of David was correlated to its high density of coordination sites (DOCS).

AB - Two- and three-dimensional metallosupramolecules shaped like a Star of David were synthesized by the self-assembly of a tetratopic pyridyl ligand with a 180° diplatinum(II) motif and PdII ions, respectively. In contrast to other strategies, such as template-directed synthesis and stepwise self-assembly, this design enables the formation of 2D and 3D structures in one step and high yield. The structures were characterized by both one-dimensional (1H, 13C, 31P) and two-dimensional (COSY, NOESY, DOSY) NMR spectroscopy, ESI-MS, ion-mobility mass spectrometry (IM–MS), AFM, and TEM. The stabilities of the 2D and 3D structures were measured and compared by gradient tandem mass spectrometry (gMS2). The high stability of the 3D Star of David was correlated to its high density of coordination sites (DOCS).

KW - ion-mobility mass spectrometry

KW - metallosupramolecules

KW - multitopic ligands

KW - self-assembly

KW - supramolecular chemistry

UR - https://www.scopus.com/pages/publications/85017353176

U2 - 10.1002/anie.201701417

DO - 10.1002/anie.201701417

M3 - 文章

C2 - 28382756

AN - SCOPUS:85017353176

SN - 1433-7851

VL - 56

SP - 5258

EP - 5262

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 19

ER -

Direct Self-Assembly of a 2D and 3D Star of David

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Keywords

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