Direct observation of ordered oxygen defects on the atomic scale in Li2O2 for Li-O2 batteries

Dongdong Xiao; Shanmu Dong; Jing Guan; Lin Gu; Shanming Li; Nijie Zhao; Chaoqun Shang; Zhenzhong Yang; Hao Zheng; Chun Chen; Ruijuan Xiao; Yong Sheng Hu; Hong Li; Guanglei Cui; Liquan Chen

doi:10.1002/aenm.201400664

Direct observation of ordered oxygen defects on the atomic scale in Li₂O₂ for Li-O₂ batteries

Dongdong Xiao
, Shanmu Dong
, Jing Guan
, Lin Gu^*
, Shanming Li
, Nijie Zhao
, Chaoqun Shang
, Zhenzhong Yang
, Hao Zheng
, Chun Chen
, Ruijuan Xiao
, Yong Sheng Hu
, Hong Li
, Guanglei Cui
, Liquan Chen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The structure of the discharge product, Li₂O₂, in lithium-oxygen batteries is revealed directly on the atomic scale. A unique stage ordering that the peroxide vacancy occupies preferentially in every other layer along the c-axis of Li₂O₂ is observed. This finding provides new insight into the relationship between the structure of Li₂O₂ and the discharge/charge behavior of Li-O₂ batteries.

Original language	English
Article number	1400664
Journal	Advanced Energy Materials
Volume	5
Issue number	3
DOIs	https://doi.org/10.1002/aenm.201400664
State	Published - 1 Feb 2015
Externally published	Yes

Keywords

atomic-scale structures
lithium peroxide
lithium-oxygen batteries
oxygen defects

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/aenm.201400664

Cite this

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title = "Direct observation of ordered oxygen defects on the atomic scale in Li2O2 for Li-O2 batteries",

abstract = "The structure of the discharge product, Li2O2, in lithium-oxygen batteries is revealed directly on the atomic scale. A unique stage ordering that the peroxide vacancy occupies preferentially in every other layer along the c-axis of Li2O2 is observed. This finding provides new insight into the relationship between the structure of Li2O2 and the discharge/charge behavior of Li-O2 batteries.",

keywords = "atomic-scale structures, lithium peroxide, lithium-oxygen batteries, oxygen defects",

author = "Dongdong Xiao and Shanmu Dong and Jing Guan and Lin Gu and Shanming Li and Nijie Zhao and Chaoqun Shang and Zhenzhong Yang and Hao Zheng and Chun Chen and Ruijuan Xiao and Hu, \{Yong Sheng\} and Hong Li and Guanglei Cui and Liquan Chen",

note = "Publisher Copyright: {\textcopyright} 2014 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

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doi = "10.1002/aenm.201400664",

language = "英语",

volume = "5",

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TY - JOUR

T1 - Direct observation of ordered oxygen defects on the atomic scale in Li2O2 for Li-O2 batteries

AU - Xiao, Dongdong

AU - Dong, Shanmu

AU - Guan, Jing

AU - Gu, Lin

AU - Li, Shanming

AU - Zhao, Nijie

AU - Shang, Chaoqun

AU - Yang, Zhenzhong

AU - Zheng, Hao

AU - Chen, Chun

AU - Xiao, Ruijuan

AU - Hu, Yong Sheng

AU - Li, Hong

AU - Cui, Guanglei

AU - Chen, Liquan

PY - 2015/2/1

Y1 - 2015/2/1

N2 - The structure of the discharge product, Li2O2, in lithium-oxygen batteries is revealed directly on the atomic scale. A unique stage ordering that the peroxide vacancy occupies preferentially in every other layer along the c-axis of Li2O2 is observed. This finding provides new insight into the relationship between the structure of Li2O2 and the discharge/charge behavior of Li-O2 batteries.

AB - The structure of the discharge product, Li2O2, in lithium-oxygen batteries is revealed directly on the atomic scale. A unique stage ordering that the peroxide vacancy occupies preferentially in every other layer along the c-axis of Li2O2 is observed. This finding provides new insight into the relationship between the structure of Li2O2 and the discharge/charge behavior of Li-O2 batteries.

KW - atomic-scale structures

KW - lithium peroxide

KW - lithium-oxygen batteries

KW - oxygen defects

UR - https://www.scopus.com/pages/publications/84922341039

U2 - 10.1002/aenm.201400664

DO - 10.1002/aenm.201400664

M3 - 文章

AN - SCOPUS:84922341039

SN - 1614-6832

VL - 5

JO - Advanced Energy Materials

JF - Advanced Energy Materials

IS - 3

M1 - 1400664

ER -