Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

Cong Bin Ji; Yun Lin Liu; Xiao Li Zhao; Yin Long Guo; Hao Yang Wang; Jian Zhou

doi:10.1039/c2ob06746c

Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

Cong Bin Ji
, Yun Lin Liu
, Xiao Li Zhao
, Yin Long Guo^*
, Hao Yang Wang
, Jian Zhou

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

We report the first example of catalytic asymmetric direct amination of α-monosubstituted nitroacetates using di-tert-butyl azodicarboxylate. The simple and easily available Hatakeyama's catalyst β-ICD 11 was found to be a highly enantioselective catalyst for this reaction.

Original language	English
Pages (from-to)	1158-1161
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	10
Issue number	6
DOIs	https://doi.org/10.1039/c2ob06746c
State	Published - 14 Feb 2012

Access to Document

10.1039/c2ob06746c

Cite this

@article{06d01d0e02264c7195ae9369772425d3,

title = "Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD",

abstract = "We report the first example of catalytic asymmetric direct amination of α-monosubstituted nitroacetates using di-tert-butyl azodicarboxylate. The simple and easily available Hatakeyama's catalyst β-ICD 11 was found to be a highly enantioselective catalyst for this reaction.",

author = "Ji, \{Cong Bin\} and Liu, \{Yun Lin\} and Zhao, \{Xiao Li\} and Guo, \{Yin Long\} and Wang, \{Hao Yang\} and Jian Zhou",

year = "2012",

month = feb,

day = "14",

doi = "10.1039/c2ob06746c",

language = "英语",

volume = "10",

pages = "1158--1161",

journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

number = "6",

}

TY - JOUR

T1 - Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

AU - Ji, Cong Bin

AU - Liu, Yun Lin

AU - Zhao, Xiao Li

AU - Guo, Yin Long

AU - Wang, Hao Yang

AU - Zhou, Jian

PY - 2012/2/14

Y1 - 2012/2/14

N2 - We report the first example of catalytic asymmetric direct amination of α-monosubstituted nitroacetates using di-tert-butyl azodicarboxylate. The simple and easily available Hatakeyama's catalyst β-ICD 11 was found to be a highly enantioselective catalyst for this reaction.

AB - We report the first example of catalytic asymmetric direct amination of α-monosubstituted nitroacetates using di-tert-butyl azodicarboxylate. The simple and easily available Hatakeyama's catalyst β-ICD 11 was found to be a highly enantioselective catalyst for this reaction.

UR - https://www.scopus.com/pages/publications/84862908458

U2 - 10.1039/c2ob06746c

DO - 10.1039/c2ob06746c

M3 - 文章

C2 - 22231285

AN - SCOPUS:84862908458

SN - 1477-0520

VL - 10

SP - 1158

EP - 1161

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 6

ER -

Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

Abstract

Access to Document

Other files and links

Fingerprint

Cite this