Di -μ Chloridobis-{[4-chloro-2-(dimethylaminomethyl)phenyl- κ2 C 1,N]palladium(II)}

Yankui Sang; Qiaomin Hong; Wenwei Qiu; Qiancai Liu; Fan Yang

doi:10.1107/S1600536810003569

Di -μ Chloridobis-{[4-chloro-2-(dimethylaminomethyl)phenyl- κ² C ¹,N]palladium(II)}

Yankui Sang, Qiaomin Hong, Wenwei Qiu, Qiancai Liu, Fan Yang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The title compound, [Pd₂(C₉H₁₁ClN) ₂Cl₂], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl-amino-meth-yl)phenyl ligand, forming a five-membered ring (N - Pd - C - C - C). In the crystal structure, weak C - H ⋯Cl hydrogen bonds link the mol-ecules in rows.

Original language	English
Pages (from-to)	m252
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	3
DOIs	https://doi.org/10.1107/S1600536810003569
State	Published - 2010

Keywords

Data-to-parameter ratio = 19.5
Mean σ(C-C) = 0.005 Å
R factor = 0.032
Single-crystal X-ray study
T = 296 K
WR factor = 0.087

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@article{f8dfcdad55154bf79a0fd889ce3e7f14,

title = "Di -μ Chloridobis-\{[4-chloro-2-(dimethylaminomethyl)phenyl- κ2 C 1,N]palladium(II)\}",

abstract = "The title compound, [Pd2(C9H11ClN) 2Cl2], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl-amino-meth-yl)phenyl ligand, forming a five-membered ring (N - Pd - C - C - C). In the crystal structure, weak C - H ⋯Cl hydrogen bonds link the mol-ecules in rows.",

keywords = "Data-to-parameter ratio = 19.5, Mean σ(C-C) = 0.005 {\AA}, R factor = 0.032, Single-crystal X-ray study, T = 296 K, WR factor = 0.087",

author = "Yankui Sang and Qiaomin Hong and Wenwei Qiu and Qiancai Liu and Fan Yang",

year = "2010",

doi = "10.1107/S1600536810003569",

language = "英语",

volume = "66",

pages = "m252",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "3",

}

TY - JOUR

T1 - Di -μ Chloridobis-{[4-chloro-2-(dimethylaminomethyl)phenyl- κ2 C 1,N]palladium(II)}

AU - Sang, Yankui

AU - Hong, Qiaomin

AU - Qiu, Wenwei

AU - Liu, Qiancai

AU - Yang, Fan

PY - 2010

Y1 - 2010

N2 - The title compound, [Pd2(C9H11ClN) 2Cl2], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl-amino-meth-yl)phenyl ligand, forming a five-membered ring (N - Pd - C - C - C). In the crystal structure, weak C - H ⋯Cl hydrogen bonds link the mol-ecules in rows.

AB - The title compound, [Pd2(C9H11ClN) 2Cl2], consists of two Pd atoms which are bridged by two Cl atoms, forming a centrosymmetric binuclear complex with a square-planar coordination for each of the Pd atoms. The Pd atom is chelated by one N and one C atom from a 4-chloro-2-(dimethyl-amino-meth-yl)phenyl ligand, forming a five-membered ring (N - Pd - C - C - C). In the crystal structure, weak C - H ⋯Cl hydrogen bonds link the mol-ecules in rows.

KW - Data-to-parameter ratio = 19.5

KW - Mean σ(C-C) = 0.005 Å

KW - R factor = 0.032

KW - Single-crystal X-ray study

KW - T = 296 K

KW - WR factor = 0.087

UR - https://www.scopus.com/pages/publications/77949349400

U2 - 10.1107/S1600536810003569

DO - 10.1107/S1600536810003569

M3 - 文章

AN - SCOPUS:77949349400

SN - 1600-5368

VL - 66

SP - m252

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -

Di -μ Chloridobis-{[4-chloro-2-(dimethylaminomethyl)phenyl- κ² C ¹,N]palladium(II)}

Abstract

Keywords

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