Design and construction of supramolecular polysulfurated metallodendrimers with various shapes and sizes via coordination-driven self-assembly

Nai Wei Wu; Quan Jie Li; Jing Zhang; Jiuming He; Jiang Kun Ou-Yang; Hongwei Tan; Zeper Abliz; Hai Bo Yang

doi:10.1016/j.tet.2013.04.058

Design and construction of supramolecular polysulfurated metallodendrimers with various shapes and sizes via coordination-driven self-assembly

Nai Wei Wu
, Quan Jie Li
, Jing Zhang
, Jiuming He
, Jiang Kun Ou-Yang
, Hongwei Tan
, Zeper Abliz
, Hai Bo Yang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University
Beijing Normal University
Chinese Academy of Medical Sciences

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A new family of 120 polysulfurated dipyridine donors have been successfully designed and synthesized, from which a series of novel rhomboidal and hexagonal supramolecular polysulfurated metallodendrimers were prepared via coordination-driven self-assembly. The structures of the newly designed polysulfurated metallodendrimers were characterized by multinuclear NMR ( ¹H and ³¹P), mass spectrometry (CSI-TOF-MS), and elemental analysis. Moreover, the shape and size of these novel metallodendrimers were investigated with PM6 semi-empirical molecular orbital methods.

Original language	English
Pages (from-to)	5981-5988
Number of pages	8
Journal	Tetrahedron
Volume	69
Issue number	29
DOIs	https://doi.org/10.1016/j.tet.2013.04.058
State	Published - 22 Jul 2013

Access to Document

10.1016/j.tet.2013.04.058

Cite this

@article{2e0b37fdea154c2e96b9ff837b323043,

title = "Design and construction of supramolecular polysulfurated metallodendrimers with various shapes and sizes via coordination-driven self-assembly",

abstract = "A new family of 120 polysulfurated dipyridine donors have been successfully designed and synthesized, from which a series of novel rhomboidal and hexagonal supramolecular polysulfurated metallodendrimers were prepared via coordination-driven self-assembly. The structures of the newly designed polysulfurated metallodendrimers were characterized by multinuclear NMR ( 1H and 31P), mass spectrometry (CSI-TOF-MS), and elemental analysis. Moreover, the shape and size of these novel metallodendrimers were investigated with PM6 semi-empirical molecular orbital methods.",

author = "Wu, \{Nai Wei\} and Li, \{Quan Jie\} and Jing Zhang and Jiuming He and Ou-Yang, \{Jiang Kun\} and Hongwei Tan and Zeper Abliz and Yang, \{Hai Bo\}",

year = "2013",

month = jul,

day = "22",

doi = "10.1016/j.tet.2013.04.058",

language = "英语",

volume = "69",

pages = "5981--5988",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Ltd",

number = "29",

}

TY - JOUR

T1 - Design and construction of supramolecular polysulfurated metallodendrimers with various shapes and sizes via coordination-driven self-assembly

AU - Wu, Nai Wei

AU - Li, Quan Jie

AU - Zhang, Jing

AU - He, Jiuming

AU - Ou-Yang, Jiang Kun

AU - Tan, Hongwei

AU - Abliz, Zeper

AU - Yang, Hai Bo

PY - 2013/7/22

Y1 - 2013/7/22

N2 - A new family of 120 polysulfurated dipyridine donors have been successfully designed and synthesized, from which a series of novel rhomboidal and hexagonal supramolecular polysulfurated metallodendrimers were prepared via coordination-driven self-assembly. The structures of the newly designed polysulfurated metallodendrimers were characterized by multinuclear NMR ( 1H and 31P), mass spectrometry (CSI-TOF-MS), and elemental analysis. Moreover, the shape and size of these novel metallodendrimers were investigated with PM6 semi-empirical molecular orbital methods.

AB - A new family of 120 polysulfurated dipyridine donors have been successfully designed and synthesized, from which a series of novel rhomboidal and hexagonal supramolecular polysulfurated metallodendrimers were prepared via coordination-driven self-assembly. The structures of the newly designed polysulfurated metallodendrimers were characterized by multinuclear NMR ( 1H and 31P), mass spectrometry (CSI-TOF-MS), and elemental analysis. Moreover, the shape and size of these novel metallodendrimers were investigated with PM6 semi-empirical molecular orbital methods.

UR - https://www.scopus.com/pages/publications/84878891126

U2 - 10.1016/j.tet.2013.04.058

DO - 10.1016/j.tet.2013.04.058

M3 - 文章

AN - SCOPUS:84878891126

SN - 0040-4020

VL - 69

SP - 5981

EP - 5988

JO - Tetrahedron

JF - Tetrahedron

IS - 29

ER -

Design and construction of supramolecular polysulfurated metallodendrimers with various shapes and sizes via coordination-driven self-assembly

Abstract

Access to Document

Other files and links

Fingerprint

Cite this