Design and construction of supramolecular polysulfurated metallodendrimers with various shapes and sizes via coordination-driven self-assembly

Nai Wei Wu, Quan Jie Li, Jing Zhang, Jiuming He, Jiang Kun Ou-Yang, Hongwei Tan, Zeper Abliz, Hai Bo Yang

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

A new family of 120 polysulfurated dipyridine donors have been successfully designed and synthesized, from which a series of novel rhomboidal and hexagonal supramolecular polysulfurated metallodendrimers were prepared via coordination-driven self-assembly. The structures of the newly designed polysulfurated metallodendrimers were characterized by multinuclear NMR ( 1H and 31P), mass spectrometry (CSI-TOF-MS), and elemental analysis. Moreover, the shape and size of these novel metallodendrimers were investigated with PM6 semi-empirical molecular orbital methods.

Original languageEnglish
Pages (from-to)5981-5988
Number of pages8
JournalTetrahedron
Volume69
Issue number29
DOIs
StatePublished - 22 Jul 2013

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