Abstract
A new family of 120 polysulfurated dipyridine donors have been successfully designed and synthesized, from which a series of novel rhomboidal and hexagonal supramolecular polysulfurated metallodendrimers were prepared via coordination-driven self-assembly. The structures of the newly designed polysulfurated metallodendrimers were characterized by multinuclear NMR ( 1H and 31P), mass spectrometry (CSI-TOF-MS), and elemental analysis. Moreover, the shape and size of these novel metallodendrimers were investigated with PM6 semi-empirical molecular orbital methods.
| Original language | English |
|---|---|
| Pages (from-to) | 5981-5988 |
| Number of pages | 8 |
| Journal | Tetrahedron |
| Volume | 69 |
| Issue number | 29 |
| DOIs | |
| State | Published - 22 Jul 2013 |