Design and construction of endo -functionalized multiferrocenyl hexagons via coordination-driven self-assembly and their electrochemistry

Li Jun Chen; Quan Jie Li; Jiuming He; Hongwei Tan; Zeper Abliz; Hai Bo Yang

doi:10.1021/jo201979d

Design and construction of endo -functionalized multiferrocenyl hexagons via coordination-driven self-assembly and their electrochemistry

Li Jun Chen
, Quan Jie Li
, Jiuming He
, Hongwei Tan
, Zeper Abliz
, Hai Bo Yang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

The construction of a new family of endo-functionalized multiferrocenyl hexagons with various sizes via coordination-driven self-assembly is described. The structures of these novel metallacycles, containing several ferrocenyl moieties at their interior surface, are characterized by multinuclear NMR ( ³¹P and ¹H) spectroscopy, cold-spray ionization mass spectrometry (CSI-TOF-MS), elemental analysis, and molecular modeling. Insight into the structural and electrochemical properties of these endo-functionalized multiferrocenyl hexagons was obtained through cyclic voltammetry investigation.

Original language	English
Pages (from-to)	1148-1153
Number of pages	6
Journal	Journal of Organic Chemistry
Volume	77
Issue number	2
DOIs	https://doi.org/10.1021/jo201979d
State	Published - 20 Jan 2012

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abstract = "The construction of a new family of endo-functionalized multiferrocenyl hexagons with various sizes via coordination-driven self-assembly is described. The structures of these novel metallacycles, containing several ferrocenyl moieties at their interior surface, are characterized by multinuclear NMR ( 31P and 1H) spectroscopy, cold-spray ionization mass spectrometry (CSI-TOF-MS), elemental analysis, and molecular modeling. Insight into the structural and electrochemical properties of these endo-functionalized multiferrocenyl hexagons was obtained through cyclic voltammetry investigation.",

author = "Chen, \{Li Jun\} and Li, \{Quan Jie\} and Jiuming He and Hongwei Tan and Zeper Abliz and Yang, \{Hai Bo\}",

year = "2012",

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T1 - Design and construction of endo -functionalized multiferrocenyl hexagons via coordination-driven self-assembly and their electrochemistry

AU - Chen, Li Jun

AU - Li, Quan Jie

AU - He, Jiuming

AU - Tan, Hongwei

AU - Abliz, Zeper

AU - Yang, Hai Bo

PY - 2012/1/20

Y1 - 2012/1/20

N2 - The construction of a new family of endo-functionalized multiferrocenyl hexagons with various sizes via coordination-driven self-assembly is described. The structures of these novel metallacycles, containing several ferrocenyl moieties at their interior surface, are characterized by multinuclear NMR ( 31P and 1H) spectroscopy, cold-spray ionization mass spectrometry (CSI-TOF-MS), elemental analysis, and molecular modeling. Insight into the structural and electrochemical properties of these endo-functionalized multiferrocenyl hexagons was obtained through cyclic voltammetry investigation.

AB - The construction of a new family of endo-functionalized multiferrocenyl hexagons with various sizes via coordination-driven self-assembly is described. The structures of these novel metallacycles, containing several ferrocenyl moieties at their interior surface, are characterized by multinuclear NMR ( 31P and 1H) spectroscopy, cold-spray ionization mass spectrometry (CSI-TOF-MS), elemental analysis, and molecular modeling. Insight into the structural and electrochemical properties of these endo-functionalized multiferrocenyl hexagons was obtained through cyclic voltammetry investigation.

UR - https://www.scopus.com/pages/publications/84862962431

U2 - 10.1021/jo201979d

DO - 10.1021/jo201979d

M3 - 文章

C2 - 22191387

AN - SCOPUS:84862962431

SN - 0022-3263

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SP - 1148

EP - 1153

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 2

ER -

Design and construction of endo -functionalized multiferrocenyl hexagons via coordination-driven self-assembly and their electrochemistry

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