Deperturbation of the rotational spectrum of the d3Δ- a3π (7, 1) band of CS radical

Chuanliang Li; Lunhua Deng; Jing Zhang; Xuanbing Qiu; Jilin Wei; Yangqin Chen

doi:10.1016/j.jms.2013.02.002

Deperturbation of the rotational spectrum of the d³Δ- a³π (7, 1) band of CS radical

Chuanliang Li
, Lunhua Deng^*
, Jing Zhang
, Xuanbing Qiu
, Jilin Wei
, Yangqin Chen

^*Corresponding author for this work

Taiyuan University of Science and Technology
East China Normal University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The spectra of d³Δ-a³π (7, 1) band of CS radical were measured by optical heterodyne-concentration modulation spectroscopy in the region from 11 640 to 12 230 cm^-1. In total, we assigned three hundred and four lines, of which R_ee and R _ff branches in the d³Δ₁-a ³π₀ subsystem and more than a hundred lines were first observed and identified. The anomalous lambda-doubling of the d ³Δ₁ (υ = 7) level reveals a local perturbation interaction from the ¹Σ^- state. The perturbation parameter between ¹Σ^- and a³π ₀ (υ = 13), and molecular constants of the d³Δ ₁ (υ = 7) as well as ¹Σ^- were derived through fitting all assigned lines to the effective Hamiltonian. Crown

Original language	English
Pages (from-to)	29-32
Number of pages	4
Journal	Journal of Molecular Spectroscopy
Volume	284-285
DOIs	https://doi.org/10.1016/j.jms.2013.02.002
State	Published - 2013
Externally published	Yes

Keywords

Carbon monosulfide radical
Deperturbation analysis
Laser absorption spectroscopy
Molecular constants

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10.1016/j.jms.2013.02.002

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title = "Deperturbation of the rotational spectrum of the d3Δ- a3π (7, 1) band of CS radical",

abstract = "The spectra of d3Δ-a3π (7, 1) band of CS radical were measured by optical heterodyne-concentration modulation spectroscopy in the region from 11 640 to 12 230 cm-1. In total, we assigned three hundred and four lines, of which Ree and R ff branches in the d3Δ1-a 3π0 subsystem and more than a hundred lines were first observed and identified. The anomalous lambda-doubling of the d 3Δ1 (υ = 7) level reveals a local perturbation interaction from the 1Σ- state. The perturbation parameter between 1Σ- and a3π 0 (υ = 13), and molecular constants of the d3Δ 1 (υ = 7) as well as 1Σ- were derived through fitting all assigned lines to the effective Hamiltonian. Crown",

keywords = "Carbon monosulfide radical, Deperturbation analysis, Laser absorption spectroscopy, Molecular constants",

author = "Chuanliang Li and Lunhua Deng and Jing Zhang and Xuanbing Qiu and Jilin Wei and Yangqin Chen",

year = "2013",

doi = "10.1016/j.jms.2013.02.002",

language = "英语",

volume = "284-285",

pages = "29--32",

journal = "Journal of Molecular Spectroscopy",

issn = "0022-2852",

publisher = "Academic Press Inc.",

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TY - JOUR

T1 - Deperturbation of the rotational spectrum of the d3Δ- a3π (7, 1) band of CS radical

AU - Li, Chuanliang

AU - Deng, Lunhua

AU - Zhang, Jing

AU - Qiu, Xuanbing

AU - Wei, Jilin

AU - Chen, Yangqin

PY - 2013

Y1 - 2013

N2 - The spectra of d3Δ-a3π (7, 1) band of CS radical were measured by optical heterodyne-concentration modulation spectroscopy in the region from 11 640 to 12 230 cm-1. In total, we assigned three hundred and four lines, of which Ree and R ff branches in the d3Δ1-a 3π0 subsystem and more than a hundred lines were first observed and identified. The anomalous lambda-doubling of the d 3Δ1 (υ = 7) level reveals a local perturbation interaction from the 1Σ- state. The perturbation parameter between 1Σ- and a3π 0 (υ = 13), and molecular constants of the d3Δ 1 (υ = 7) as well as 1Σ- were derived through fitting all assigned lines to the effective Hamiltonian. Crown

AB - The spectra of d3Δ-a3π (7, 1) band of CS radical were measured by optical heterodyne-concentration modulation spectroscopy in the region from 11 640 to 12 230 cm-1. In total, we assigned three hundred and four lines, of which Ree and R ff branches in the d3Δ1-a 3π0 subsystem and more than a hundred lines were first observed and identified. The anomalous lambda-doubling of the d 3Δ1 (υ = 7) level reveals a local perturbation interaction from the 1Σ- state. The perturbation parameter between 1Σ- and a3π 0 (υ = 13), and molecular constants of the d3Δ 1 (υ = 7) as well as 1Σ- were derived through fitting all assigned lines to the effective Hamiltonian. Crown

KW - Carbon monosulfide radical

KW - Deperturbation analysis

KW - Laser absorption spectroscopy

KW - Molecular constants

UR - https://www.scopus.com/pages/publications/84874852365

U2 - 10.1016/j.jms.2013.02.002

DO - 10.1016/j.jms.2013.02.002

M3 - 文章

AN - SCOPUS:84874852365

SN - 0022-2852

VL - 284-285

SP - 29

EP - 32

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

ER -

Deperturbation of the rotational spectrum of the d³Δ- a³π (7, 1) band of CS radical

Abstract

Keywords

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