Dearomatization reaction of β-naphthols with disulfurating reagents

Shan Shan Zhang; Jiahui Xue; Qing Gu; Xuefeng Jiang; Shu Li You

doi:10.1039/d1ob01731d

Dearomatization reaction of β-naphthols with disulfurating reagents

Shan Shan Zhang
, Jiahui Xue
, Qing Gu
, Xuefeng Jiang^*
, Shu Li You

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

p-TsOH-catalyzed intermolecular dearomatization reactions of β-naphthols with disulfurating reagents were developed. Various β-naphthalenones bearing a quaternary carbon stereogenic center were obtained smoothly in good to excellent yields with high chemoselectivity in the presence of 5 mol%p-TsOH. This reaction features mild reaction conditions and excellent functional group tolerance.

Original language	English
Pages (from-to)	8761-8771
Number of pages	11
Journal	Organic and Biomolecular Chemistry
Volume	19
Issue number	40
DOIs	https://doi.org/10.1039/d1ob01731d
State	Published - 28 Oct 2021

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10.1039/d1ob01731d

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title = "Dearomatization reaction of β-naphthols with disulfurating reagents",

abstract = "p-TsOH-catalyzed intermolecular dearomatization reactions of β-naphthols with disulfurating reagents were developed. Various β-naphthalenones bearing a quaternary carbon stereogenic center were obtained smoothly in good to excellent yields with high chemoselectivity in the presence of 5 mol\%p-TsOH. This reaction features mild reaction conditions and excellent functional group tolerance.",

author = "Zhang, \{Shan Shan\} and Jiahui Xue and Qing Gu and Xuefeng Jiang and You, \{Shu Li\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

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day = "28",

doi = "10.1039/d1ob01731d",

language = "英语",

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T1 - Dearomatization reaction of β-naphthols with disulfurating reagents

AU - Zhang, Shan Shan

AU - Xue, Jiahui

AU - Gu, Qing

AU - Jiang, Xuefeng

AU - You, Shu Li

PY - 2021/10/28

Y1 - 2021/10/28

N2 - p-TsOH-catalyzed intermolecular dearomatization reactions of β-naphthols with disulfurating reagents were developed. Various β-naphthalenones bearing a quaternary carbon stereogenic center were obtained smoothly in good to excellent yields with high chemoselectivity in the presence of 5 mol%p-TsOH. This reaction features mild reaction conditions and excellent functional group tolerance.

AB - p-TsOH-catalyzed intermolecular dearomatization reactions of β-naphthols with disulfurating reagents were developed. Various β-naphthalenones bearing a quaternary carbon stereogenic center were obtained smoothly in good to excellent yields with high chemoselectivity in the presence of 5 mol%p-TsOH. This reaction features mild reaction conditions and excellent functional group tolerance.

UR - https://www.scopus.com/pages/publications/85117289700

U2 - 10.1039/d1ob01731d

DO - 10.1039/d1ob01731d

M3 - 文章

AN - SCOPUS:85117289700

SN - 1477-0520

VL - 19

SP - 8761

EP - 8771

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 40

ER -

Dearomatization reaction of β-naphthols with disulfurating reagents

Abstract

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