Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts using in the Heck reactions

Fan Yang; Yangming Zhang; Rui Zheng; Jie Tang; Mingyuan He

doi:10.1016/S0022-328X(02)01195-6

Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts using in the Heck reactions

Fan Yang, Yangming Zhang, Rui Zheng, Jie Tang, Mingyuan He

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Cyclopalladated complexes of tertiary arylamines are reported in this paper as highly efficient catalysts for the Heck reactions of iodoarenes with methylacrylate. The monomeric complexes (2 and 4), which contain mixed phosphorous-nitrogen (P-N) donors, were found to be more active than the corresponding dimeric ones, which contain only single nitrogen donor. Palladium mirror was observed, indicating the involvement of classic Pd(0)/Pd(II) catalytic cycle using these cyclopalladated complexes.

Original language	English
Pages (from-to)	146-148
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	651
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(02)01195-6
State	Published - 15 May 2002

Keywords

Cyclopalladated complex
Heck reaction
Palladium catalyst
Palladium mirror

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10.1016/S0022-328X(02)01195-6

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title = "Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts using in the Heck reactions",

abstract = "Cyclopalladated complexes of tertiary arylamines are reported in this paper as highly efficient catalysts for the Heck reactions of iodoarenes with methylacrylate. The monomeric complexes (2 and 4), which contain mixed phosphorous-nitrogen (P-N) donors, were found to be more active than the corresponding dimeric ones, which contain only single nitrogen donor. Palladium mirror was observed, indicating the involvement of classic Pd(0)/Pd(II) catalytic cycle using these cyclopalladated complexes.",

keywords = "Cyclopalladated complex, Heck reaction, Palladium catalyst, Palladium mirror",

author = "Fan Yang and Yangming Zhang and Rui Zheng and Jie Tang and Mingyuan He",

year = "2002",

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T1 - Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts using in the Heck reactions

AU - Yang, Fan

AU - Zhang, Yangming

AU - Zheng, Rui

AU - Tang, Jie

AU - He, Mingyuan

PY - 2002/5/15

Y1 - 2002/5/15

N2 - Cyclopalladated complexes of tertiary arylamines are reported in this paper as highly efficient catalysts for the Heck reactions of iodoarenes with methylacrylate. The monomeric complexes (2 and 4), which contain mixed phosphorous-nitrogen (P-N) donors, were found to be more active than the corresponding dimeric ones, which contain only single nitrogen donor. Palladium mirror was observed, indicating the involvement of classic Pd(0)/Pd(II) catalytic cycle using these cyclopalladated complexes.

AB - Cyclopalladated complexes of tertiary arylamines are reported in this paper as highly efficient catalysts for the Heck reactions of iodoarenes with methylacrylate. The monomeric complexes (2 and 4), which contain mixed phosphorous-nitrogen (P-N) donors, were found to be more active than the corresponding dimeric ones, which contain only single nitrogen donor. Palladium mirror was observed, indicating the involvement of classic Pd(0)/Pd(II) catalytic cycle using these cyclopalladated complexes.

KW - Cyclopalladated complex

KW - Heck reaction

KW - Palladium catalyst

KW - Palladium mirror

UR - https://www.scopus.com/pages/publications/0037093134

U2 - 10.1016/S0022-328X(02)01195-6

DO - 10.1016/S0022-328X(02)01195-6

M3 - 文章

AN - SCOPUS:0037093134

SN - 0022-328X

VL - 651

SP - 146

EP - 148

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts using in the Heck reactions

Abstract

Keywords

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