Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts for the Heck reaction

Yang Ming Zhang*, Fan Yang, Rui Zheng, Jie Tang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

Cyclopalladated complexes of tertiary arylamines 1-4 are reported for the first time with as highly efficient catalysts for the Heck reactions turnover numbers being up to 9.6×106(mol product per mol Pd) and turnover frequencies up to 8.7×105(mol product per mol Pd per h). This is the highest catalytic activity of all Heck reactions reported to date.

Original languageEnglish
Pages (from-to)533-534
Number of pages2
JournalChinese Journal of Organic Chemistry
Volume21
Issue number7
StatePublished - 2001

Keywords

  • Catalysts
  • Cyclopalladated complexes
  • Heck reactions

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