Cyanine Lead Iodine Low-Dimensional Perovskite with ∼1000 nm Photoelectronic Response

Xiaodong Li; Yuyang Hu; Xuemin Guo; Chunyan Lu; Haobo Yuan; Wen Li; Zhengbo Cui; Yingguo Yang; Wenxiao Zhang; Junfeng Fang

doi:10.1021/acsaem.4c00568

Cyanine Lead Iodine Low-Dimensional Perovskite with ∼1000 nm Photoelectronic Response

Xiaodong Li^*
, Yuyang Hu
, Xuemin Guo
, Chunyan Lu
, Haobo Yuan
, Wen Li
, Zhengbo Cui
, Yingguo Yang
, Wenxiao Zhang
, Junfeng Fang^*

^*Corresponding author for this work

East China Normal University
Fudan University

Research output: Contribution to journal › Article › peer-review

Abstract

We report a cyanine dye (815EI)-incorporated perovskite, where the iodide salt nature of 815EI helps to interact with PbI₂ to form a low-dimensional perovskite, and the perovskite structure promotes 815EI molecule arrangement and crystallization, benefiting charge dissociation and transport. Resulting perovskite solar cells (PSCs) exhibit a broadened photoelectronic response to ∼1000 nm with obvious external quantum efficiency (EQE) of >15% at 920 nm. In addition, resulting PSCs exhibit excellent stability, retaining over 90% of initial efficiency after 85 °C aging for 2300 h. Our work provides a new approach to broaden the photoelectronic response of low-dimensional perovskite materials.

Original language	English
Pages (from-to)	4650-4654
Number of pages	5
Journal	ACS Applied Energy Materials
Volume	7
Issue number	11
DOIs	https://doi.org/10.1021/acsaem.4c00568
State	Published - 10 Jun 2024
Externally published	Yes

Keywords

Cyanine dye
Low-dimensional perovskite
Near-infrared
Photoelectronic response
Stability

Access to Document

10.1021/acsaem.4c00568

Cite this

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title = "Cyanine Lead Iodine Low-Dimensional Perovskite with ∼1000 nm Photoelectronic Response",

abstract = "We report a cyanine dye (815EI)-incorporated perovskite, where the iodide salt nature of 815EI helps to interact with PbI2 to form a low-dimensional perovskite, and the perovskite structure promotes 815EI molecule arrangement and crystallization, benefiting charge dissociation and transport. Resulting perovskite solar cells (PSCs) exhibit a broadened photoelectronic response to ∼1000 nm with obvious external quantum efficiency (EQE) of >15\% at 920 nm. In addition, resulting PSCs exhibit excellent stability, retaining over 90\% of initial efficiency after 85 °C aging for 2300 h. Our work provides a new approach to broaden the photoelectronic response of low-dimensional perovskite materials.",

keywords = "Cyanine dye, Low-dimensional perovskite, Near-infrared, Photoelectronic response, Stability",

author = "Xiaodong Li and Yuyang Hu and Xuemin Guo and Chunyan Lu and Haobo Yuan and Wen Li and Zhengbo Cui and Yingguo Yang and Wenxiao Zhang and Junfeng Fang",

note = "Publisher Copyright: {\textcopyright} 2024 American Chemical Society.",

year = "2024",

month = jun,

day = "10",

doi = "10.1021/acsaem.4c00568",

language = "英语",

volume = "7",

pages = "4650--4654",

journal = "ACS Applied Energy Materials",

issn = "2574-0962",

publisher = "American Chemical Society",

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}

TY - JOUR

T1 - Cyanine Lead Iodine Low-Dimensional Perovskite with ∼1000 nm Photoelectronic Response

AU - Li, Xiaodong

AU - Hu, Yuyang

AU - Guo, Xuemin

AU - Lu, Chunyan

AU - Yuan, Haobo

AU - Li, Wen

AU - Cui, Zhengbo

AU - Yang, Yingguo

AU - Zhang, Wenxiao

AU - Fang, Junfeng

PY - 2024/6/10

Y1 - 2024/6/10

N2 - We report a cyanine dye (815EI)-incorporated perovskite, where the iodide salt nature of 815EI helps to interact with PbI2 to form a low-dimensional perovskite, and the perovskite structure promotes 815EI molecule arrangement and crystallization, benefiting charge dissociation and transport. Resulting perovskite solar cells (PSCs) exhibit a broadened photoelectronic response to ∼1000 nm with obvious external quantum efficiency (EQE) of >15% at 920 nm. In addition, resulting PSCs exhibit excellent stability, retaining over 90% of initial efficiency after 85 °C aging for 2300 h. Our work provides a new approach to broaden the photoelectronic response of low-dimensional perovskite materials.

AB - We report a cyanine dye (815EI)-incorporated perovskite, where the iodide salt nature of 815EI helps to interact with PbI2 to form a low-dimensional perovskite, and the perovskite structure promotes 815EI molecule arrangement and crystallization, benefiting charge dissociation and transport. Resulting perovskite solar cells (PSCs) exhibit a broadened photoelectronic response to ∼1000 nm with obvious external quantum efficiency (EQE) of >15% at 920 nm. In addition, resulting PSCs exhibit excellent stability, retaining over 90% of initial efficiency after 85 °C aging for 2300 h. Our work provides a new approach to broaden the photoelectronic response of low-dimensional perovskite materials.

KW - Cyanine dye

KW - Low-dimensional perovskite

KW - Near-infrared

KW - Photoelectronic response

KW - Stability

UR - https://www.scopus.com/pages/publications/85194951724

U2 - 10.1021/acsaem.4c00568

DO - 10.1021/acsaem.4c00568

M3 - 文章

AN - SCOPUS:85194951724

SN - 2574-0962

VL - 7

SP - 4650

EP - 4654

JO - ACS Applied Energy Materials

JF - ACS Applied Energy Materials

IS - 11

ER -

Cyanine Lead Iodine Low-Dimensional Perovskite with ∼1000 nm Photoelectronic Response

Abstract

Keywords

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