Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors

Qun Ye; Jingjing Chang; Kuo Wei Huang; Xueliang Shi; Jishan Wu; Chunyan Chi

doi:10.1021/ol400082c

Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors

Qun Ye
, Jingjing Chang
, Kuo Wei Huang
, Xueliang Shi
, Jishan Wu
, Chunyan Chi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

74 Scopus citations

Abstract

Several diazatetracene diimides with high electron affinity (up to 4.66 eV!) were prepared and well characterized. The LUMO energy level of these electron-deficient molecules was found to be closely related to their material stability. Compound 7 with ultrahigh electron affinity suffered from reduction and hydrolysis in the presence of silica gel or water. The stable compounds 3 and 6 showed n-channel FET behavior with an average electron mobility of 0.002 and 0.005 cm² V^-1 s^-1, respectively, using a solution processing method.

Original language	English
Pages (from-to)	1194-1197
Number of pages	4
Journal	Organic Letters
Volume	15
Issue number	6
DOIs	https://doi.org/10.1021/ol400082c
State	Published - 15 Mar 2013
Externally published	Yes

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title = "Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors",

abstract = "Several diazatetracene diimides with high electron affinity (up to 4.66 eV!) were prepared and well characterized. The LUMO energy level of these electron-deficient molecules was found to be closely related to their material stability. Compound 7 with ultrahigh electron affinity suffered from reduction and hydrolysis in the presence of silica gel or water. The stable compounds 3 and 6 showed n-channel FET behavior with an average electron mobility of 0.002 and 0.005 cm2 V-1 s-1, respectively, using a solution processing method.",

author = "Qun Ye and Jingjing Chang and Huang, \{Kuo Wei\} and Xueliang Shi and Jishan Wu and Chunyan Chi",

year = "2013",

month = mar,

day = "15",

doi = "10.1021/ol400082c",

language = "英语",

volume = "15",

pages = "1194--1197",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "6",

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TY - JOUR

T1 - Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors

AU - Ye, Qun

AU - Chang, Jingjing

AU - Huang, Kuo Wei

AU - Shi, Xueliang

AU - Wu, Jishan

AU - Chi, Chunyan

PY - 2013/3/15

Y1 - 2013/3/15

N2 - Several diazatetracene diimides with high electron affinity (up to 4.66 eV!) were prepared and well characterized. The LUMO energy level of these electron-deficient molecules was found to be closely related to their material stability. Compound 7 with ultrahigh electron affinity suffered from reduction and hydrolysis in the presence of silica gel or water. The stable compounds 3 and 6 showed n-channel FET behavior with an average electron mobility of 0.002 and 0.005 cm2 V-1 s-1, respectively, using a solution processing method.

AB - Several diazatetracene diimides with high electron affinity (up to 4.66 eV!) were prepared and well characterized. The LUMO energy level of these electron-deficient molecules was found to be closely related to their material stability. Compound 7 with ultrahigh electron affinity suffered from reduction and hydrolysis in the presence of silica gel or water. The stable compounds 3 and 6 showed n-channel FET behavior with an average electron mobility of 0.002 and 0.005 cm2 V-1 s-1, respectively, using a solution processing method.

UR - https://www.scopus.com/pages/publications/84875183407

U2 - 10.1021/ol400082c

DO - 10.1021/ol400082c

M3 - 文章

AN - SCOPUS:84875183407

SN - 1523-7060

VL - 15

SP - 1194

EP - 1197

JO - Organic Letters

JF - Organic Letters

IS - 6

ER -

Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors

Abstract

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