Cu/TiO₂ nanoparticles modified nitrogen-doped graphene as a highly efficient catalyst for the selective electroreduction of CO₂ to different alcohols

The construction of an efficient and robust catalyst for the electrochemical reduction of carbon dioxide into energy-rich products has recently received considerable attention. Herein, a Cu/TiO₂ nanoparticles modified nitrogen-doped graphene (Cu/TiO₂/NG) carbon material is fabricated for the selective reduction of CO₂ into different alcohols. We found the Cu/TiO₂/NG nanocomposite across a range of potentials for the electroreduction of CO₂ exhibits dual catalytic ability, possessing an outstanding ability to produce methanol (reaching a maximum faradaic efficiency of 19.5% at a potential of −0.20 V vs. the reversible hydrogen electrode (RHE)) and a capability to produce ethanol (with a high faradaic efficiency up to 43.6% at −0.75 V vs. RHE). In addition, the Cu/TiO₂/NG composite shows remarkable stability and reusability at both reductive potentials in the electrochemical process. The designed Cu/TiO₂/NG composite may offer a new simple method based on earth-abundant metals to construct robust electrocatalysts for CO₂ reduction.