Cubic mesoporous silica with large controllable entrance sizes and advanced adsorption properties

Jie Fan; Chengzhong Yu; Feng Gao; Jie Lei; Bozhi Tian; Limin Wang; Qian Luo; Bo Tu; Wuzong Zhou; Dongyuan Zhao

doi:10.1002/anie.200351027

Cubic mesoporous silica with large controllable entrance sizes and advanced adsorption properties

Jie Fan
, Chengzhong Yu^*
, Feng Gao
, Jie Lei
, Bozhi Tian
, Limin Wang
, Qian Luo
, Bo Tu
, Wuzong Zhou
, Dongyuan Zhao

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

539 Scopus citations

Abstract

Large cavities (≈10-12.3 nm) of cubic (Fm-3m) mesoporous silica without intergrowth are synthesized in the presence of block copolymer templates. The entrance sizes of these cavities can be adjusted in the range of ≈4-9 nm as confirmed by nitrogen sorption studies and an examination of the negative gold replicas. The 3D open mesostructures facilitate the transportation of biomolecules (see picture), as well as the replication of a large-pore (9 nm) cubic mesoporous carbon.

Original language	English
Pages (from-to)	3146-3150
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	27
DOIs	https://doi.org/10.1002/anie.200351027
State	Published - 14 Jul 2003
Externally published	Yes

Keywords

Adsorption
Carbon
Enzymes
Mesoporous materials
Silica

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10.1002/anie.200351027

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title = "Cubic mesoporous silica with large controllable entrance sizes and advanced adsorption properties",

abstract = "Large cavities (≈10-12.3 nm) of cubic (Fm-3m) mesoporous silica without intergrowth are synthesized in the presence of block copolymer templates. The entrance sizes of these cavities can be adjusted in the range of ≈4-9 nm as confirmed by nitrogen sorption studies and an examination of the negative gold replicas. The 3D open mesostructures facilitate the transportation of biomolecules (see picture), as well as the replication of a large-pore (9 nm) cubic mesoporous carbon.",

keywords = "Adsorption, Carbon, Enzymes, Mesoporous materials, Silica",

author = "Jie Fan and Chengzhong Yu and Feng Gao and Jie Lei and Bozhi Tian and Limin Wang and Qian Luo and Bo Tu and Wuzong Zhou and Dongyuan Zhao",

year = "2003",

month = jul,

day = "14",

doi = "10.1002/anie.200351027",

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volume = "42",

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T1 - Cubic mesoporous silica with large controllable entrance sizes and advanced adsorption properties

AU - Fan, Jie

AU - Yu, Chengzhong

AU - Gao, Feng

AU - Lei, Jie

AU - Tian, Bozhi

AU - Wang, Limin

AU - Luo, Qian

AU - Tu, Bo

AU - Zhou, Wuzong

AU - Zhao, Dongyuan

PY - 2003/7/14

Y1 - 2003/7/14

N2 - Large cavities (≈10-12.3 nm) of cubic (Fm-3m) mesoporous silica without intergrowth are synthesized in the presence of block copolymer templates. The entrance sizes of these cavities can be adjusted in the range of ≈4-9 nm as confirmed by nitrogen sorption studies and an examination of the negative gold replicas. The 3D open mesostructures facilitate the transportation of biomolecules (see picture), as well as the replication of a large-pore (9 nm) cubic mesoporous carbon.

AB - Large cavities (≈10-12.3 nm) of cubic (Fm-3m) mesoporous silica without intergrowth are synthesized in the presence of block copolymer templates. The entrance sizes of these cavities can be adjusted in the range of ≈4-9 nm as confirmed by nitrogen sorption studies and an examination of the negative gold replicas. The 3D open mesostructures facilitate the transportation of biomolecules (see picture), as well as the replication of a large-pore (9 nm) cubic mesoporous carbon.

KW - Adsorption

KW - Carbon

KW - Enzymes

KW - Mesoporous materials

KW - Silica

UR - https://www.scopus.com/pages/publications/0041810206

U2 - 10.1002/anie.200351027

DO - 10.1002/anie.200351027

M3 - 文章

AN - SCOPUS:0041810206

SN - 1433-7851

VL - 42

SP - 3146

EP - 3150

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 27

ER -

Cubic mesoporous silica with large controllable entrance sizes and advanced adsorption properties

Abstract

Keywords

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