TY - JOUR
T1 - Crystal structure of the addition compound of [Ni(meso-cth)][Cr(ox) 2(bpy)](H2O)(ClO4) with weak coordination bonds and hydrogen bonds
AU - Tang, Jin Kui
AU - Si, Shu Feng
AU - Gao, En Qing
AU - Liao, Dai Zheng
AU - Jiang, Zong Hui
AU - Yan, Shi Ping
PY - 2002
Y1 - 2002
N2 - A new ionic complex [Ni(meso-cth)][Cr(ox)2(bpy)](H 2O)(ClO4) [meso-cth = meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, ox = oxalato ainon, bpy = 2,2′-bipyridine] was prepared and its structure was determined. The complex was found to crystallized in monoclinic space group P2(1)/n, with a = 13.6000(4) Å, b = 18.763(5) Å, c = 14.995(4) Å, β = 106.958(5)°, V = 3659.9(17) Å3, and Z = 4. The structure consisted of cationic [Ni(meso-cth)]2+, anionic [Cr(ox)2(bpy)]-, and perchlorate anions; the cationic [Ni(meso-cth)]2+ and anionic [Cr(ox)2(bpy)]- units were related by weak coordination bonds and hydrogen bonds.
AB - A new ionic complex [Ni(meso-cth)][Cr(ox)2(bpy)](H 2O)(ClO4) [meso-cth = meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, ox = oxalato ainon, bpy = 2,2′-bipyridine] was prepared and its structure was determined. The complex was found to crystallized in monoclinic space group P2(1)/n, with a = 13.6000(4) Å, b = 18.763(5) Å, c = 14.995(4) Å, β = 106.958(5)°, V = 3659.9(17) Å3, and Z = 4. The structure consisted of cationic [Ni(meso-cth)]2+, anionic [Cr(ox)2(bpy)]-, and perchlorate anions; the cationic [Ni(meso-cth)]2+ and anionic [Cr(ox)2(bpy)]- units were related by weak coordination bonds and hydrogen bonds.
KW - Adduct complex
KW - Chromium(III) complex
KW - Crystal structure
KW - Macrocyclic ligands
UR - https://www.scopus.com/pages/publications/0036389273
U2 - 10.1023/A:1020213709871
DO - 10.1023/A:1020213709871
M3 - 文章
AN - SCOPUS:0036389273
SN - 1074-1542
VL - 32
SP - 331
EP - 335
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
IS - 9
ER -