Crystal structure of chiral acetato-bridged binuclear cyclopalladated complex [Pd(μ-O2CMe)(S-C6H4CHMeNH 2)]2

Fan Yang; Yi Ping Li; Juan Nie; Jie Tang; Ming Yuan He

doi:10.1002/cjoc.20030210813

Crystal structure of chiral acetato-bridged binuclear cyclopalladated complex [Pd(μ-O₂CMe)(S-C₆H₄CHMeNH ₂)]₂

Fan Yang, Yi Ping Li, Juan Nie, Jie Tang, Ming Yuan He

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Reaction of (S)-α-methylbenzylamine with Pd(OAc)₂ in anhydrous HOAc produced the chiral complex [Pd(μ-O₂CMe)(S-C ₆H₄CHMeNH₂)]₂ (1). The complex was characterized by ¹H NMR spectroscopy, elemental analysis and a single-crystal X-ray analysis. The X-ray crystal structure analysis revealed that complex 1 has four isomers: two outer and two inner isomers.

Original language	English
Pages (from-to)	1039-1042
Number of pages	4
Journal	Chinese Journal of Chemistry
Volume	21
Issue number	8
DOIs	https://doi.org/10.1002/cjoc.20030210813
State	Published - Aug 2003

Keywords

Chiral cyclopalladated complex
Crystal structure
α-methylbenzylamine

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title = "Crystal structure of chiral acetato-bridged binuclear cyclopalladated complex [Pd(μ-O2CMe)(S-C6H4CHMeNH 2)]2",

abstract = "Reaction of (S)-α-methylbenzylamine with Pd(OAc)2 in anhydrous HOAc produced the chiral complex [Pd(μ-O2CMe)(S-C 6H4CHMeNH2)]2 (1). The complex was characterized by 1H NMR spectroscopy, elemental analysis and a single-crystal X-ray analysis. The X-ray crystal structure analysis revealed that complex 1 has four isomers: two outer and two inner isomers.",

keywords = "Chiral cyclopalladated complex, Crystal structure, α-methylbenzylamine",

author = "Fan Yang and Li, \{Yi Ping\} and Juan Nie and Jie Tang and He, \{Ming Yuan\}",

year = "2003",

month = aug,

doi = "10.1002/cjoc.20030210813",

language = "英语",

volume = "21",

pages = "1039--1042",

journal = "Chinese Journal of Chemistry",

issn = "1001-604X",

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TY - JOUR

T1 - Crystal structure of chiral acetato-bridged binuclear cyclopalladated complex [Pd(μ-O2CMe)(S-C6H4CHMeNH 2)]2

AU - Yang, Fan

AU - Li, Yi Ping

AU - Nie, Juan

AU - Tang, Jie

AU - He, Ming Yuan

PY - 2003/8

Y1 - 2003/8

N2 - Reaction of (S)-α-methylbenzylamine with Pd(OAc)2 in anhydrous HOAc produced the chiral complex [Pd(μ-O2CMe)(S-C 6H4CHMeNH2)]2 (1). The complex was characterized by 1H NMR spectroscopy, elemental analysis and a single-crystal X-ray analysis. The X-ray crystal structure analysis revealed that complex 1 has four isomers: two outer and two inner isomers.

AB - Reaction of (S)-α-methylbenzylamine with Pd(OAc)2 in anhydrous HOAc produced the chiral complex [Pd(μ-O2CMe)(S-C 6H4CHMeNH2)]2 (1). The complex was characterized by 1H NMR spectroscopy, elemental analysis and a single-crystal X-ray analysis. The X-ray crystal structure analysis revealed that complex 1 has four isomers: two outer and two inner isomers.

KW - Chiral cyclopalladated complex

KW - Crystal structure

KW - α-methylbenzylamine

UR - https://www.scopus.com/pages/publications/3042766632

U2 - 10.1002/cjoc.20030210813

DO - 10.1002/cjoc.20030210813

M3 - 文章

AN - SCOPUS:3042766632

SN - 1001-604X

VL - 21

SP - 1039

EP - 1042

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 8

ER -

Crystal structure of chiral acetato-bridged binuclear cyclopalladated complex [Pd(μ-O₂CMe)(S-C₆H₄CHMeNH ₂)]₂

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Keywords

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