Covalent post-functionalization of Zeolitic imidazolate framework ZIF-90 membrane for enhanced hydrogen selectivity

Aisheng Huang; Jürgen Caro

doi:10.1002/anie.201007861

Covalent post-functionalization of Zeolitic imidazolate framework ZIF-90 membrane for enhanced hydrogen selectivity

Aisheng Huang^*
, Jürgen Caro

^*Corresponding author for this work

Leibniz University Hannover

Research output: Contribution to journal › Article › peer-review

272 Scopus citations

Abstract

MOF constrictor: Covalent modification of a ZIF-90 membrane was achieved by imine condensation of the aldehyde groups of the metal-organic framework (MOF) linker by ethanolamine (see picture). The modification leads to constriction of the pore apertures and prevents unselective permeation through defect pores, thus improving gas separation performance. For a H₂/CO₂ mixture, selectivity can be increased from 7.3 to 62.5.

Original language	English
Pages (from-to)	4979-4982
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	21
DOIs	https://doi.org/10.1002/anie.201007861
State	Published - 16 May 2011
Externally published	Yes

Keywords

imidazolate
membranes
metal-organic frameworks
molecular sieves
post-synthetic modification

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10.1002/anie.201007861

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abstract = "MOF constrictor: Covalent modification of a ZIF-90 membrane was achieved by imine condensation of the aldehyde groups of the metal-organic framework (MOF) linker by ethanolamine (see picture). The modification leads to constriction of the pore apertures and prevents unselective permeation through defect pores, thus improving gas separation performance. For a H2/CO2 mixture, selectivity can be increased from 7.3 to 62.5.",

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AU - Huang, Aisheng

AU - Caro, Jürgen

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N2 - MOF constrictor: Covalent modification of a ZIF-90 membrane was achieved by imine condensation of the aldehyde groups of the metal-organic framework (MOF) linker by ethanolamine (see picture). The modification leads to constriction of the pore apertures and prevents unselective permeation through defect pores, thus improving gas separation performance. For a H2/CO2 mixture, selectivity can be increased from 7.3 to 62.5.

AB - MOF constrictor: Covalent modification of a ZIF-90 membrane was achieved by imine condensation of the aldehyde groups of the metal-organic framework (MOF) linker by ethanolamine (see picture). The modification leads to constriction of the pore apertures and prevents unselective permeation through defect pores, thus improving gas separation performance. For a H2/CO2 mixture, selectivity can be increased from 7.3 to 62.5.

KW - imidazolate

KW - membranes

KW - metal-organic frameworks

KW - molecular sieves

KW - post-synthetic modification

UR - https://www.scopus.com/pages/publications/79955751784

U2 - 10.1002/anie.201007861

DO - 10.1002/anie.201007861

M3 - 文章

C2 - 21472930

AN - SCOPUS:79955751784

SN - 1433-7851

VL - 50

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 21

ER -

Covalent post-functionalization of Zeolitic imidazolate framework ZIF-90 membrane for enhanced hydrogen selectivity

Abstract

Keywords

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