Copper(II) and cobalt(II) coordination polymers with azido ions and 1,3-bis(4′-pyridyl)propane

En Qing Gao; Yan Xia Xu; Ai Ling Cheng; Ming Yuan He; Chun Hua Yan

doi:10.1016/j.inoche.2005.11.004

Copper(II) and cobalt(II) coordination polymers with azido ions and 1,3-bis(4′-pyridyl)propane

En Qing Gao^*
, Yan Xia Xu
, Ai Ling Cheng
, Ming Yuan He
, Chun Hua Yan

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A copper(II) complex [Cu(μ-1,3-N₃)(N₃)(bpp)] _n (1) (bpp = 1,3-bis(4′-pyridyl)propane) has been shown to exhibit a two-dimensional network formed by the bpp ligands interlinking copper(II)-azido chains, in which the single azido bridge assumes an asymmetric μ-1,3 mode and mediates weak ferromagnetic coupling. On the other hand, the reaction of cobalt(II), azido and bpp yielded two supramolecular isomers of [Co(N₃)₂(bpp)₂]_n (2 and 3) in which the azido ions serve as terminal ligands and the metal ions are linked by the bpp ligands in different conformations.

Original language	English
Pages (from-to)	212-215
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	9
Issue number	2
DOIs	https://doi.org/10.1016/j.inoche.2005.11.004
State	Published - Feb 2006

Keywords

Azide
Coordination polymers
Crystal structures
Magnetic properties
Supramolecular isomerism

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10.1016/j.inoche.2005.11.004

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@article{a191b5621b12487e8a5a7c1cfce2e161,

title = "Copper(II) and cobalt(II) coordination polymers with azido ions and 1,3-bis(4′-pyridyl)propane",

abstract = "A copper(II) complex [Cu(μ-1,3-N3)(N3)(bpp)] n (1) (bpp = 1,3-bis(4′-pyridyl)propane) has been shown to exhibit a two-dimensional network formed by the bpp ligands interlinking copper(II)-azido chains, in which the single azido bridge assumes an asymmetric μ-1,3 mode and mediates weak ferromagnetic coupling. On the other hand, the reaction of cobalt(II), azido and bpp yielded two supramolecular isomers of [Co(N3)2(bpp)2]n (2 and 3) in which the azido ions serve as terminal ligands and the metal ions are linked by the bpp ligands in different conformations.",

keywords = "Azide, Coordination polymers, Crystal structures, Magnetic properties, Supramolecular isomerism",

author = "Gao, \{En Qing\} and Xu, \{Yan Xia\} and Cheng, \{Ai Ling\} and He, \{Ming Yuan\} and Yan, \{Chun Hua\}",

year = "2006",

month = feb,

doi = "10.1016/j.inoche.2005.11.004",

language = "英语",

volume = "9",

pages = "212--215",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Copper(II) and cobalt(II) coordination polymers with azido ions and 1,3-bis(4′-pyridyl)propane

AU - Gao, En Qing

AU - Xu, Yan Xia

AU - Cheng, Ai Ling

AU - He, Ming Yuan

AU - Yan, Chun Hua

PY - 2006/2

Y1 - 2006/2

N2 - A copper(II) complex [Cu(μ-1,3-N3)(N3)(bpp)] n (1) (bpp = 1,3-bis(4′-pyridyl)propane) has been shown to exhibit a two-dimensional network formed by the bpp ligands interlinking copper(II)-azido chains, in which the single azido bridge assumes an asymmetric μ-1,3 mode and mediates weak ferromagnetic coupling. On the other hand, the reaction of cobalt(II), azido and bpp yielded two supramolecular isomers of [Co(N3)2(bpp)2]n (2 and 3) in which the azido ions serve as terminal ligands and the metal ions are linked by the bpp ligands in different conformations.

AB - A copper(II) complex [Cu(μ-1,3-N3)(N3)(bpp)] n (1) (bpp = 1,3-bis(4′-pyridyl)propane) has been shown to exhibit a two-dimensional network formed by the bpp ligands interlinking copper(II)-azido chains, in which the single azido bridge assumes an asymmetric μ-1,3 mode and mediates weak ferromagnetic coupling. On the other hand, the reaction of cobalt(II), azido and bpp yielded two supramolecular isomers of [Co(N3)2(bpp)2]n (2 and 3) in which the azido ions serve as terminal ligands and the metal ions are linked by the bpp ligands in different conformations.

KW - Azide

KW - Coordination polymers

KW - Crystal structures

KW - Magnetic properties

KW - Supramolecular isomerism

UR - https://www.scopus.com/pages/publications/31344459906

U2 - 10.1016/j.inoche.2005.11.004

DO - 10.1016/j.inoche.2005.11.004

M3 - 文章

AN - SCOPUS:31344459906

SN - 1387-7003

VL - 9

SP - 212

EP - 215

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 2

ER -

Copper(II) and cobalt(II) coordination polymers with azido ions and 1,3-bis(4′-pyridyl)propane

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Keywords

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