Copper-catalysed: Ortho -selective C-H bond functionalization of phenols and naphthols with α-aryl-α-diazoesters

Ben Ma; Zhiqiong Tang; Junliang Zhang; Lu Liu

doi:10.1039/d0cc04495d

Copper-catalysed: Ortho -selective C-H bond functionalization of phenols and naphthols with α-aryl-α-diazoesters

Ben Ma
, Zhiqiong Tang
, Junliang Zhang^*
, Lu Liu^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University
Fudan University

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

Herein, we reported the first copper-catalyzed highly efficient C(sp2)-H functionalization of unprotected naphthols and phenols with α-aryl-α-diazoesters. In this transformation, CuCl2 efficiently promoted the highly chemo- and site-selective C-H bond functionalization under mild conditions, furnishing diverse phenol derivatives in moderate to excellent yields from readily available starting materials.

Original language	English
Pages (from-to)	9485-9488
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	66
DOIs	https://doi.org/10.1039/d0cc04495d
State	Published - 25 Aug 2020

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title = "Copper-catalysed: Ortho -selective C-H bond functionalization of phenols and naphthols with α-aryl-α-diazoesters",

abstract = "Herein, we reported the first copper-catalyzed highly efficient C(sp2)-H functionalization of unprotected naphthols and phenols with α-aryl-α-diazoesters. In this transformation, CuCl2 efficiently promoted the highly chemo- and site-selective C-H bond functionalization under mild conditions, furnishing diverse phenol derivatives in moderate to excellent yields from readily available starting materials.",

author = "Ben Ma and Zhiqiong Tang and Junliang Zhang and Lu Liu",

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T2 - Ortho -selective C-H bond functionalization of phenols and naphthols with α-aryl-α-diazoesters

AU - Ma, Ben

AU - Tang, Zhiqiong

AU - Zhang, Junliang

AU - Liu, Lu

PY - 2020/8/25

Y1 - 2020/8/25

N2 - Herein, we reported the first copper-catalyzed highly efficient C(sp2)-H functionalization of unprotected naphthols and phenols with α-aryl-α-diazoesters. In this transformation, CuCl2 efficiently promoted the highly chemo- and site-selective C-H bond functionalization under mild conditions, furnishing diverse phenol derivatives in moderate to excellent yields from readily available starting materials.

AB - Herein, we reported the first copper-catalyzed highly efficient C(sp2)-H functionalization of unprotected naphthols and phenols with α-aryl-α-diazoesters. In this transformation, CuCl2 efficiently promoted the highly chemo- and site-selective C-H bond functionalization under mild conditions, furnishing diverse phenol derivatives in moderate to excellent yields from readily available starting materials.

UR - https://www.scopus.com/pages/publications/85089712603

U2 - 10.1039/d0cc04495d

DO - 10.1039/d0cc04495d

M3 - 文章

C2 - 32678391

AN - SCOPUS:85089712603

SN - 1359-7345

VL - 56

SP - 9485

EP - 9488

JO - Chemical Communications

JF - Chemical Communications

IS - 66

ER -

Copper-catalysed: Ortho -selective C-H bond functionalization of phenols and naphthols with α-aryl-α-diazoesters

Abstract

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