Coordination-driven self-assembly of metallodendrimers possessing well-defined and controllable cavities as cores

Hai Bo Yang; Adam M. Hawkridge; Songping D. Huang; Neeladri Das; Scott D. Bunge; David C. Muddiman; Peter J. Stang

doi:10.1021/ja066804h

Coordination-driven self-assembly of metallodendrimers possessing well-defined and controllable cavities as cores

Hai Bo Yang^*
, Adam M. Hawkridge
, Songping D. Huang
, Neeladri Das
, Scott D. Bunge
, David C. Muddiman
, Peter J. Stang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

132 Scopus citations

Abstract

The design and self-assembly of novel cavity-cored metallodendrimers via noncovalent interactions are described. By employing [G0]-[G3] 120° ditopic donor linkers substituted with Fréchet-type dendrons and appropriate rigid di-Pt(II) acceptor subunits, [G0]-[G3]-rhomboidal metallodendrimers and [G0]-[G3]-hexagonal, "snowflake-shaped" metallodendrimers with well-defined shape and size were prepared under mild conditions in high yields. The assemblies were characterized with multinuclear NMR (¹H and ³¹P), mass spectrometry (ESI-MS and ESI-FT-ICR-MS), and elemental analysis. Isotopically resolved mass spectrometry data support the existence of the metallodendrimers with rhomboidal and hexagonal cavities, and NMR data are consistent with the formation of all ensembles. The structures of [G0]- and [G1]-rhomboidal metallodendrimers were unambiguously confirmed via single-crystal X-ray crystallography. The shape and size of two [G3]-hexagonal metallodendrimers were investigated with MM2 force-field modeling.

Original language	English
Pages (from-to)	2120-2129
Number of pages	10
Journal	Journal of the American Chemical Society
Volume	129
Issue number	7
DOIs	https://doi.org/10.1021/ja066804h
State	Published - 21 Feb 2007
Externally published	Yes

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@article{4119d878883e47ef99eaef56583ab9a3,

title = "Coordination-driven self-assembly of metallodendrimers possessing well-defined and controllable cavities as cores",

abstract = "The design and self-assembly of novel cavity-cored metallodendrimers via noncovalent interactions are described. By employing [G0]-[G3] 120° ditopic donor linkers substituted with Fr{\'e}chet-type dendrons and appropriate rigid di-Pt(II) acceptor subunits, [G0]-[G3]-rhomboidal metallodendrimers and [G0]-[G3]-hexagonal, {"}snowflake-shaped{"} metallodendrimers with well-defined shape and size were prepared under mild conditions in high yields. The assemblies were characterized with multinuclear NMR (1H and 31P), mass spectrometry (ESI-MS and ESI-FT-ICR-MS), and elemental analysis. Isotopically resolved mass spectrometry data support the existence of the metallodendrimers with rhomboidal and hexagonal cavities, and NMR data are consistent with the formation of all ensembles. The structures of [G0]- and [G1]-rhomboidal metallodendrimers were unambiguously confirmed via single-crystal X-ray crystallography. The shape and size of two [G3]-hexagonal metallodendrimers were investigated with MM2 force-field modeling.",

author = "Yang, \{Hai Bo\} and Hawkridge, \{Adam M.\} and Huang, \{Songping D.\} and Neeladri Das and Bunge, \{Scott D.\} and Muddiman, \{David C.\} and Stang, \{Peter J.\}",

year = "2007",

month = feb,

day = "21",

doi = "10.1021/ja066804h",

language = "英语",

volume = "129",

pages = "2120--2129",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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}

TY - JOUR

T1 - Coordination-driven self-assembly of metallodendrimers possessing well-defined and controllable cavities as cores

AU - Yang, Hai Bo

AU - Hawkridge, Adam M.

AU - Huang, Songping D.

AU - Das, Neeladri

AU - Bunge, Scott D.

AU - Muddiman, David C.

AU - Stang, Peter J.

PY - 2007/2/21

Y1 - 2007/2/21

N2 - The design and self-assembly of novel cavity-cored metallodendrimers via noncovalent interactions are described. By employing [G0]-[G3] 120° ditopic donor linkers substituted with Fréchet-type dendrons and appropriate rigid di-Pt(II) acceptor subunits, [G0]-[G3]-rhomboidal metallodendrimers and [G0]-[G3]-hexagonal, "snowflake-shaped" metallodendrimers with well-defined shape and size were prepared under mild conditions in high yields. The assemblies were characterized with multinuclear NMR (1H and 31P), mass spectrometry (ESI-MS and ESI-FT-ICR-MS), and elemental analysis. Isotopically resolved mass spectrometry data support the existence of the metallodendrimers with rhomboidal and hexagonal cavities, and NMR data are consistent with the formation of all ensembles. The structures of [G0]- and [G1]-rhomboidal metallodendrimers were unambiguously confirmed via single-crystal X-ray crystallography. The shape and size of two [G3]-hexagonal metallodendrimers were investigated with MM2 force-field modeling.

AB - The design and self-assembly of novel cavity-cored metallodendrimers via noncovalent interactions are described. By employing [G0]-[G3] 120° ditopic donor linkers substituted with Fréchet-type dendrons and appropriate rigid di-Pt(II) acceptor subunits, [G0]-[G3]-rhomboidal metallodendrimers and [G0]-[G3]-hexagonal, "snowflake-shaped" metallodendrimers with well-defined shape and size were prepared under mild conditions in high yields. The assemblies were characterized with multinuclear NMR (1H and 31P), mass spectrometry (ESI-MS and ESI-FT-ICR-MS), and elemental analysis. Isotopically resolved mass spectrometry data support the existence of the metallodendrimers with rhomboidal and hexagonal cavities, and NMR data are consistent with the formation of all ensembles. The structures of [G0]- and [G1]-rhomboidal metallodendrimers were unambiguously confirmed via single-crystal X-ray crystallography. The shape and size of two [G3]-hexagonal metallodendrimers were investigated with MM2 force-field modeling.

UR - https://www.scopus.com/pages/publications/33847334292

U2 - 10.1021/ja066804h

DO - 10.1021/ja066804h

M3 - 文章

C2 - 17256935

AN - SCOPUS:33847334292

SN - 0002-7863

VL - 129

SP - 2120

EP - 2129

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 7

ER -

Coordination-driven self-assembly of metallodendrimers possessing well-defined and controllable cavities as cores

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