Conversion efficiency limits and optimized designs for tandem solar cells with realistic sub-cell material quality

  • Lin Zhu*
  • , Toshimitsu Mochizuki
  • , Masahiro Yoshita
  • , Shaoqiang Chen
  • , Shintaroh Sato
  • , Changsu Kim
  • , Hidefumi Akiyama
  • , Yoshihiko Kanemitsu
  • *Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

4 Scopus citations

Abstract

To examine practical efficiency limits of tandem solar cells, we calculated conversion efficiency (ηsc) and optimized sub-cell band-gap energies (Eg) in 1-, 2-, 3-, 4-, and 5-junction cells via a detailed-balance theory, taking account of the realistic internal luminescence quantum yields (yint) of the sub-cell materials. We found that ηsc drastically decreases as the geometric mean yint∗ of all sub-cells' yint drops from 1 to 0.1, and decreases proportionally to logyint ∗ in the low-yint ∗ region. Even with moderate material quality with yint ∗ = 0.001, ηsc above 30% (35%) should be still available in 2-junction (3-junction) tandem cells, though we need optimized designs with much higher Eg than those known for the ideal cases with yint ∗ = 1.

Original languageEnglish
Title of host publication2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014
PublisherInstitute of Electrical and Electronics Engineers Inc.
Pages3404-3408
Number of pages5
ISBN (Electronic)9781479943982
DOIs
StatePublished - 15 Oct 2014
Externally publishedYes
Event40th IEEE Photovoltaic Specialist Conference, PVSC 2014 - Denver, United States
Duration: 8 Jun 201413 Jun 2014

Publication series

Name2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014

Conference

Conference40th IEEE Photovoltaic Specialist Conference, PVSC 2014
Country/TerritoryUnited States
CityDenver
Period8/06/1413/06/14

Keywords

  • Design optimization
  • Energy efficiency
  • Luminescence
  • Photovoltaic cells
  • Semiconductor materials
  • Solar power generation

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