Control of supramolecular rectangle self-assembly with a molecular template

Shan Shan Li; Hui Juan Yan; Li Jun Wan; Hai Bo Yang; Brian H. Northrop; Peter J. Stang

doi:10.1021/ja0733282

Control of supramolecular rectangle self-assembly with a molecular template

Shan Shan Li
, Hui Juan Yan
, Li Jun Wan^*
, Hai Bo Yang
, Brian H. Northrop
, Peter J. Stang

^*Corresponding author for this work

CAS - Institute of Chemistry
University of Utah

Research output: Contribution to journal › Article › peer-review

84 Scopus citations

Abstract

A facile method for controlling the self-assembly of supramolecular metallocycles on a highly oriented pyrolytic graphite (HOPG) surface is described. The process was demonstrated using 1,3,5-tris(10-carboxydecyloxy)benzene (TCDB), which self-assembles to form a stable monolayer with nanoscale cavities on HOPG, to template the deposition of supramolecular rectangles. Molecular distribution is controlled and monodispersion is achieved as the metallocycles self-organize into the cavities of the TCDB template.

Original language	English
Pages (from-to)	9268-9269
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	30
DOIs	https://doi.org/10.1021/ja0733282
State	Published - 1 Aug 2007
Externally published	Yes

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10.1021/ja0733282

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title = "Control of supramolecular rectangle self-assembly with a molecular template",

abstract = "A facile method for controlling the self-assembly of supramolecular metallocycles on a highly oriented pyrolytic graphite (HOPG) surface is described. The process was demonstrated using 1,3,5-tris(10-carboxydecyloxy)benzene (TCDB), which self-assembles to form a stable monolayer with nanoscale cavities on HOPG, to template the deposition of supramolecular rectangles. Molecular distribution is controlled and monodispersion is achieved as the metallocycles self-organize into the cavities of the TCDB template.",

author = "Li, \{Shan Shan\} and Yan, \{Hui Juan\} and Wan, \{Li Jun\} and Yang, \{Hai Bo\} and Northrop, \{Brian H.\} and Stang, \{Peter J.\}",

year = "2007",

month = aug,

day = "1",

doi = "10.1021/ja0733282",

language = "英语",

volume = "129",

pages = "9268--9269",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Control of supramolecular rectangle self-assembly with a molecular template

AU - Li, Shan Shan

AU - Yan, Hui Juan

AU - Wan, Li Jun

AU - Yang, Hai Bo

AU - Northrop, Brian H.

AU - Stang, Peter J.

PY - 2007/8/1

Y1 - 2007/8/1

N2 - A facile method for controlling the self-assembly of supramolecular metallocycles on a highly oriented pyrolytic graphite (HOPG) surface is described. The process was demonstrated using 1,3,5-tris(10-carboxydecyloxy)benzene (TCDB), which self-assembles to form a stable monolayer with nanoscale cavities on HOPG, to template the deposition of supramolecular rectangles. Molecular distribution is controlled and monodispersion is achieved as the metallocycles self-organize into the cavities of the TCDB template.

AB - A facile method for controlling the self-assembly of supramolecular metallocycles on a highly oriented pyrolytic graphite (HOPG) surface is described. The process was demonstrated using 1,3,5-tris(10-carboxydecyloxy)benzene (TCDB), which self-assembles to form a stable monolayer with nanoscale cavities on HOPG, to template the deposition of supramolecular rectangles. Molecular distribution is controlled and monodispersion is achieved as the metallocycles self-organize into the cavities of the TCDB template.

UR - https://www.scopus.com/pages/publications/34547670272

U2 - 10.1021/ja0733282

DO - 10.1021/ja0733282

M3 - 文章

C2 - 17622151

AN - SCOPUS:34547670272

SN - 0002-7863

VL - 129

SP - 9268

EP - 9269

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 30

ER -

Control of supramolecular rectangle self-assembly with a molecular template

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