Construction of porphyrin-containing metallacycle with improved stability and activity within mesoporous carbon

Li Jun Chen; Shangjun Chen; Yi Qin; Lin Xu; Guang Qiang Yin; Jun Long Zhu; Fan Fan Zhu; Wei Zheng; Xiaopeng Li; Hai Bo Yang

doi:10.1021/jacs.8b02386

Construction of porphyrin-containing metallacycle with improved stability and activity within mesoporous carbon

Li Jun Chen
, Shangjun Chen
, Yi Qin
, Lin Xu
, Guang Qiang Yin
, Jun Long Zhu
, Fan Fan Zhu
, Wei Zheng
, Xiaopeng Li^*
, Hai Bo Yang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

129 Scopus citations

Abstract

The successful construction of porphyrin functionalized metallacycle in the confined cavity of mesoporous carbon FDU-16 (3⊂C) is presented in this study. Because of high dispersity of metallacycles within the mesoporous cavities, the stability and activity of porphyrin-containing metallacycles were obviously improved. For example, ¹O₂ generation efficiency of 3⊂C is ca. 6-fold faster than that of free metallaycles in solution. Thus, the resultant hybrid material has been successfully employed as a heterogeneous catalyst for photooxidation of sulfides.

Original language	English
Pages (from-to)	5049-5052
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	140
Issue number	15
DOIs	https://doi.org/10.1021/jacs.8b02386
State	Published - 18 Apr 2018

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title = "Construction of porphyrin-containing metallacycle with improved stability and activity within mesoporous carbon",

abstract = "The successful construction of porphyrin functionalized metallacycle in the confined cavity of mesoporous carbon FDU-16 (3⊂C) is presented in this study. Because of high dispersity of metallacycles within the mesoporous cavities, the stability and activity of porphyrin-containing metallacycles were obviously improved. For example, 1O2 generation efficiency of 3⊂C is ca. 6-fold faster than that of free metallaycles in solution. Thus, the resultant hybrid material has been successfully employed as a heterogeneous catalyst for photooxidation of sulfides.",

author = "Chen, \{Li Jun\} and Shangjun Chen and Yi Qin and Lin Xu and Yin, \{Guang Qiang\} and Zhu, \{Jun Long\} and Zhu, \{Fan Fan\} and Wei Zheng and Xiaopeng Li and Yang, \{Hai Bo\}",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = apr,

day = "18",

doi = "10.1021/jacs.8b02386",

language = "英语",

volume = "140",

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journal = "Journal of the American Chemical Society",

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TY - JOUR

T1 - Construction of porphyrin-containing metallacycle with improved stability and activity within mesoporous carbon

AU - Chen, Li Jun

AU - Chen, Shangjun

AU - Qin, Yi

AU - Xu, Lin

AU - Yin, Guang Qiang

AU - Zhu, Jun Long

AU - Zhu, Fan Fan

AU - Zheng, Wei

AU - Li, Xiaopeng

AU - Yang, Hai Bo

PY - 2018/4/18

Y1 - 2018/4/18

N2 - The successful construction of porphyrin functionalized metallacycle in the confined cavity of mesoporous carbon FDU-16 (3⊂C) is presented in this study. Because of high dispersity of metallacycles within the mesoporous cavities, the stability and activity of porphyrin-containing metallacycles were obviously improved. For example, 1O2 generation efficiency of 3⊂C is ca. 6-fold faster than that of free metallaycles in solution. Thus, the resultant hybrid material has been successfully employed as a heterogeneous catalyst for photooxidation of sulfides.

AB - The successful construction of porphyrin functionalized metallacycle in the confined cavity of mesoporous carbon FDU-16 (3⊂C) is presented in this study. Because of high dispersity of metallacycles within the mesoporous cavities, the stability and activity of porphyrin-containing metallacycles were obviously improved. For example, 1O2 generation efficiency of 3⊂C is ca. 6-fold faster than that of free metallaycles in solution. Thus, the resultant hybrid material has been successfully employed as a heterogeneous catalyst for photooxidation of sulfides.

UR - https://www.scopus.com/pages/publications/85045626612

U2 - 10.1021/jacs.8b02386

DO - 10.1021/jacs.8b02386

M3 - 文章

C2 - 29625011

AN - SCOPUS:85045626612

SN - 0002-7863

VL - 140

SP - 5049

EP - 5052

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 15

ER -

Construction of porphyrin-containing metallacycle with improved stability and activity within mesoporous carbon

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