Construction of polyrotaxanes via reversible chain exchange between acylhydrazone bonds

  • Yi Jiang
  • , Jieli Wu
  • , Lin He
  • , Chunlai Tu
  • , Xinyuan Zhu*
  • , Qun Chen
  • , Yefeng Yao
  • , Deyue Yan
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

By simply heating mixtures of α-cyclodextrins and dumbbell-like poly(ethylene glycol) derivatives at 120°C, polyrotaxanes form spontaneously via reversible chain exchange between acylhydrazone bonds, which have been proven by analyses of diffusion-ordered NMR, WAXD, 1H NMR, solid-state 13C CP/MAS NMR, DSC and UV-Vis together.

Original languageEnglish
Pages (from-to)6351-6353
Number of pages3
JournalChemical Communications
Issue number47
DOIs
StatePublished - 2008

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