Abstract
By simply heating mixtures of α-cyclodextrins and dumbbell-like poly(ethylene glycol) derivatives at 120°C, polyrotaxanes form spontaneously via reversible chain exchange between acylhydrazone bonds, which have been proven by analyses of diffusion-ordered NMR, WAXD, 1H NMR, solid-state 13C CP/MAS NMR, DSC and UV-Vis together.
| Original language | English |
|---|---|
| Pages (from-to) | 6351-6353 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Issue number | 47 |
| DOIs | |
| State | Published - 2008 |