Composite pulses in directly and indirectly detected ¹⁴N MAS overtone spectroscopy

¹⁴N MAS overtone spectroscopy is mainly limited by narrow excitation bandwidths owing to the use of very long pulses to get stronger signals. We previously reported the use of modified 90° composite pulses for broadband excitation in ¹H-{NOTDQ14} D-HMQC experiments at ultra-fast MAS. In this work, we modified the 180° composite pulses, which are originally designed for spin 1/2 nuclei, for both indirect detection in ¹H-{NOTDQ14} D-HMQC experiment and direct detection in one-pulse experiment, and found that the modified 180° composite pulses are useful for broadband excitation. Furthermore, we found that the bandwidth can be tailored by simply adjusting the total pulse length.