Competitive oxidation of N, N-diethylamine with H2O2 catalyzed by TS-1

Xiujuan Deng; Lu Shen; Shuo Zhang; Yueming Liu

doi:10.3724/SP.J.1088.2011.10543

Competitive oxidation of N, N-diethylamine with H₂O₂ catalyzed by TS-1

Xiujuan Deng
, Lu Shen
, Shuo Zhang
, Yueming Liu^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Oxidation of N, N-diethylamine (DEA) to N, N-diethylhydroxylamine (DEHA) in the catalytic system of TS-1/H₂O₂ has been studied. The competitive reactions between the oxidation of DEA and DEHA were further investigated. The results suggested that the conversion of DEA and effective utilization of H₂O₂ can be increased dramatically when H₂O₂ was added dropwise, while the mole ratio of DEA/H₂O₂ greatly influenced the selectivity for DEHA. TS-1 can catalyze the oxidation of DEA, as well as the oxidation of DEHA.

Original language	English
Pages (from-to)	1550-1556
Number of pages	7
Journal	Chinese Journal of Catalysis
Volume	32
Issue number	9
DOIs	https://doi.org/10.3724/SP.J.1088.2011.10543
State	Published - Sep 2011

Keywords

Hydrogen peroxide
N, N-diethylamine
N, N-diethylhydroxylamine
Oxidation
Titanium silicalite zeolite

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10.3724/SP.J.1088.2011.10543

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title = "Competitive oxidation of N, N-diethylamine with H2O2 catalyzed by TS-1",

abstract = "Oxidation of N, N-diethylamine (DEA) to N, N-diethylhydroxylamine (DEHA) in the catalytic system of TS-1/H2O2 has been studied. The competitive reactions between the oxidation of DEA and DEHA were further investigated. The results suggested that the conversion of DEA and effective utilization of H2O2 can be increased dramatically when H2O2 was added dropwise, while the mole ratio of DEA/H2O2 greatly influenced the selectivity for DEHA. TS-1 can catalyze the oxidation of DEA, as well as the oxidation of DEHA.",

keywords = "Hydrogen peroxide, N, N-diethylamine, N, N-diethylhydroxylamine, Oxidation, Titanium silicalite zeolite",

author = "Xiujuan Deng and Lu Shen and Shuo Zhang and Yueming Liu",

year = "2011",

month = sep,

doi = "10.3724/SP.J.1088.2011.10543",

language = "英语",

volume = "32",

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journal = "Chinese Journal of Catalysis",

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TY - JOUR

T1 - Competitive oxidation of N, N-diethylamine with H2O2 catalyzed by TS-1

AU - Deng, Xiujuan

AU - Shen, Lu

AU - Zhang, Shuo

AU - Liu, Yueming

PY - 2011/9

Y1 - 2011/9

N2 - Oxidation of N, N-diethylamine (DEA) to N, N-diethylhydroxylamine (DEHA) in the catalytic system of TS-1/H2O2 has been studied. The competitive reactions between the oxidation of DEA and DEHA were further investigated. The results suggested that the conversion of DEA and effective utilization of H2O2 can be increased dramatically when H2O2 was added dropwise, while the mole ratio of DEA/H2O2 greatly influenced the selectivity for DEHA. TS-1 can catalyze the oxidation of DEA, as well as the oxidation of DEHA.

AB - Oxidation of N, N-diethylamine (DEA) to N, N-diethylhydroxylamine (DEHA) in the catalytic system of TS-1/H2O2 has been studied. The competitive reactions between the oxidation of DEA and DEHA were further investigated. The results suggested that the conversion of DEA and effective utilization of H2O2 can be increased dramatically when H2O2 was added dropwise, while the mole ratio of DEA/H2O2 greatly influenced the selectivity for DEHA. TS-1 can catalyze the oxidation of DEA, as well as the oxidation of DEHA.

KW - Hydrogen peroxide

KW - N, N-diethylamine

KW - N, N-diethylhydroxylamine

KW - Oxidation

KW - Titanium silicalite zeolite

UR - https://www.scopus.com/pages/publications/80054780344

U2 - 10.3724/SP.J.1088.2011.10543

DO - 10.3724/SP.J.1088.2011.10543

M3 - 文章

AN - SCOPUS:80054780344

SN - 1872-2067

VL - 32

SP - 1550

EP - 1556

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 9

ER -

Competitive oxidation of N, N-diethylamine with H₂O₂ catalyzed by TS-1

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Keywords

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