[Co(H2O)(HPO4)]·H2O: The layered divalent metal monohydrogenphosphate structure

Yong Kui Shan; Li Yi Dai; Shu Yuan Yu; Sheng Rong Ye; Ming Yuan He

doi:10.1002/cjoc.20020200108

[Co(H₂O)(HPO₄)]·H₂O: The layered divalent metal monohydrogenphosphate structure

Yong Kui Shan^*
, Li Yi Dai
, Shu Yuan Yu
, Sheng Rong Ye
, Ming Yuan He

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

Abstract

A new layered divalent metal monohydrogenphosphate [Co(H ₂O)(HPO₄)] · H₂O (1) was hydrothermally synthesized from the reaction of CoCl₂·6H₂O with H₃PO₄ in the presence of cis-Pt (NH₃) ₂Cl₂ and ethylenediamine. The structure features extensive intra- and inter-layer hydrogen bonding among the hydrogenphosphate anoin, the coordinated water and the crystallization water. X-ray cristallographic parameters for 1 are orthorhombic Pnma (# 62), a = 1.7528(2), b = 0.56158(7), c = 0.47867(6) nm, V = 0.47116(9) nm³, Z = 4.

Original language	English
Pages (from-to)	34-38
Number of pages	5
Journal	Chinese Journal of Chemistry
Volume	20
Issue number	1
DOIs	https://doi.org/10.1002/cjoc.20020200108
State	Published - Jan 2002

Keywords

Hydrongen bonding
Hydrothermal reaction
Monohydrogenphosphate
Structure

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title = "[Co(H2O)(HPO4)]·H2O: The layered divalent metal monohydrogenphosphate structure",

abstract = "A new layered divalent metal monohydrogenphosphate [Co(H 2O)(HPO4)] · H2O (1) was hydrothermally synthesized from the reaction of CoCl2·6H2O with H3PO4 in the presence of cis-Pt (NH3) 2Cl2 and ethylenediamine. The structure features extensive intra- and inter-layer hydrogen bonding among the hydrogenphosphate anoin, the coordinated water and the crystallization water. X-ray cristallographic parameters for 1 are orthorhombic Pnma (\# 62), a = 1.7528(2), b = 0.56158(7), c = 0.47867(6) nm, V = 0.47116(9) nm3, Z = 4.",

keywords = "Hydrongen bonding, Hydrothermal reaction, Monohydrogenphosphate, Structure",

author = "Shan, \{Yong Kui\} and Dai, \{Li Yi\} and Yu, \{Shu Yuan\} and Ye, \{Sheng Rong\} and He, \{Ming Yuan\}",

year = "2002",

month = jan,

doi = "10.1002/cjoc.20020200108",

language = "英语",

volume = "20",

pages = "34--38",

journal = "Chinese Journal of Chemistry",

issn = "1001-604X",

publisher = "John Wiley and Sons Inc",

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}

TY - JOUR

T1 - [Co(H2O)(HPO4)]·H2O

T2 - The layered divalent metal monohydrogenphosphate structure

AU - Shan, Yong Kui

AU - Dai, Li Yi

AU - Yu, Shu Yuan

AU - Ye, Sheng Rong

AU - He, Ming Yuan

PY - 2002/1

Y1 - 2002/1

N2 - A new layered divalent metal monohydrogenphosphate [Co(H 2O)(HPO4)] · H2O (1) was hydrothermally synthesized from the reaction of CoCl2·6H2O with H3PO4 in the presence of cis-Pt (NH3) 2Cl2 and ethylenediamine. The structure features extensive intra- and inter-layer hydrogen bonding among the hydrogenphosphate anoin, the coordinated water and the crystallization water. X-ray cristallographic parameters for 1 are orthorhombic Pnma (# 62), a = 1.7528(2), b = 0.56158(7), c = 0.47867(6) nm, V = 0.47116(9) nm3, Z = 4.

AB - A new layered divalent metal monohydrogenphosphate [Co(H 2O)(HPO4)] · H2O (1) was hydrothermally synthesized from the reaction of CoCl2·6H2O with H3PO4 in the presence of cis-Pt (NH3) 2Cl2 and ethylenediamine. The structure features extensive intra- and inter-layer hydrogen bonding among the hydrogenphosphate anoin, the coordinated water and the crystallization water. X-ray cristallographic parameters for 1 are orthorhombic Pnma (# 62), a = 1.7528(2), b = 0.56158(7), c = 0.47867(6) nm, V = 0.47116(9) nm3, Z = 4.

KW - Hydrongen bonding

KW - Hydrothermal reaction

KW - Monohydrogenphosphate

KW - Structure

UR - https://www.scopus.com/pages/publications/27544500950

U2 - 10.1002/cjoc.20020200108

DO - 10.1002/cjoc.20020200108

M3 - 文章

AN - SCOPUS:27544500950

SN - 1001-604X

VL - 20

SP - 34

EP - 38

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 1

ER -

[Co(H₂O)(HPO₄)]·H₂O: The layered divalent metal monohydrogenphosphate structure

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