"Click Chemistry" Mediated Functional Microporous Organic Nanotube Networks for Heterogeneous Catalysis

Wei Yu; Minghong Zhou; Tianqi Wang; Zidong He; Buyin Shi; Yang Xu; Kun Huang

doi:10.1021/acs.orglett.7b02682

"Click Chemistry" Mediated Functional Microporous Organic Nanotube Networks for Heterogeneous Catalysis

Wei Yu, Minghong Zhou, Tianqi Wang, Zidong He^*, Buyin Shi, Yang Xu, Kun Huang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The synthesis of azide functional microporous organic nanotube networks (N₃-MONNs) via a Friedel-Crafts hyper-cross-linking reaction is reported. Subsequently, a general method for obtaining heterogeneous catalysts through a Cu-catalyzed alkyne-azide reaction is presented. The small-molecule catalysts such as 2,2,6,6,-tetramethylpiperidine-1-oyl and 4-(N,N-dimethylamino)pyridine can be anchored into the MONNs. Owing to the hierarchically porous structure and high surface area, these catalysts show high activity in selective oxidation of alcohols and acylation reaction, respectively.

Original language	English
Pages (from-to)	5776-5779
Number of pages	4
Journal	Organic Letters
Volume	19
Issue number	21
DOIs	https://doi.org/10.1021/acs.orglett.7b02682
State	Published - 3 Nov 2017

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title = "{"}Click Chemistry{"} Mediated Functional Microporous Organic Nanotube Networks for Heterogeneous Catalysis",

abstract = "The synthesis of azide functional microporous organic nanotube networks (N3-MONNs) via a Friedel-Crafts hyper-cross-linking reaction is reported. Subsequently, a general method for obtaining heterogeneous catalysts through a Cu-catalyzed alkyne-azide reaction is presented. The small-molecule catalysts such as 2,2,6,6,-tetramethylpiperidine-1-oyl and 4-(N,N-dimethylamino)pyridine can be anchored into the MONNs. Owing to the hierarchically porous structure and high surface area, these catalysts show high activity in selective oxidation of alcohols and acylation reaction, respectively.",

author = "Wei Yu and Minghong Zhou and Tianqi Wang and Zidong He and Buyin Shi and Yang Xu and Kun Huang",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

month = nov,

day = "3",

doi = "10.1021/acs.orglett.7b02682",

language = "英语",

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T1 - "Click Chemistry" Mediated Functional Microporous Organic Nanotube Networks for Heterogeneous Catalysis

AU - Yu, Wei

AU - Zhou, Minghong

AU - Wang, Tianqi

AU - He, Zidong

AU - Shi, Buyin

AU - Xu, Yang

AU - Huang, Kun

PY - 2017/11/3

Y1 - 2017/11/3

N2 - The synthesis of azide functional microporous organic nanotube networks (N3-MONNs) via a Friedel-Crafts hyper-cross-linking reaction is reported. Subsequently, a general method for obtaining heterogeneous catalysts through a Cu-catalyzed alkyne-azide reaction is presented. The small-molecule catalysts such as 2,2,6,6,-tetramethylpiperidine-1-oyl and 4-(N,N-dimethylamino)pyridine can be anchored into the MONNs. Owing to the hierarchically porous structure and high surface area, these catalysts show high activity in selective oxidation of alcohols and acylation reaction, respectively.

AB - The synthesis of azide functional microporous organic nanotube networks (N3-MONNs) via a Friedel-Crafts hyper-cross-linking reaction is reported. Subsequently, a general method for obtaining heterogeneous catalysts through a Cu-catalyzed alkyne-azide reaction is presented. The small-molecule catalysts such as 2,2,6,6,-tetramethylpiperidine-1-oyl and 4-(N,N-dimethylamino)pyridine can be anchored into the MONNs. Owing to the hierarchically porous structure and high surface area, these catalysts show high activity in selective oxidation of alcohols and acylation reaction, respectively.

UR - https://www.scopus.com/pages/publications/85032955345

U2 - 10.1021/acs.orglett.7b02682

DO - 10.1021/acs.orglett.7b02682

M3 - 文章

C2 - 29072468

AN - SCOPUS:85032955345

SN - 1523-7060

VL - 19

SP - 5776

EP - 5779

JO - Organic Letters

JF - Organic Letters

IS - 21

ER -

"Click Chemistry" Mediated Functional Microporous Organic Nanotube Networks for Heterogeneous Catalysis

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