Characterization of key intermediates in a complex organocatalytic cascade reaction using mass spectrometry

Wolfgang Schrader; Peni Purwa Handayani; Jian Zhou; Benjamin List

doi:10.1002/anie.200804353

Characterization of key intermediates in a complex organocatalytic cascade reaction using mass spectrometry

Wolfgang Schrader^*, Peni Purwa Handayani, Jian Zhou, Benjamin List

^*Corresponding author for this work

Max Planck Institute for Coal Research

Research output: Contribution to journal › Article › peer-review

90 Scopus citations

Abstract

Chemical scrabble: Mechanistic studies of complex organocatalytic cascade reactions are challenging owing to the presence of many species involved. Electrospray ionization mass spectrometry provides details about a one-pot quadruple organocatalytic cascade reaction, and allows detailed characterization of the reaction and its key intermediates.

Original language	English
Pages (from-to)	1463-1466
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	8
DOIs	https://doi.org/10.1002/anie.200804353
State	Published - 9 Feb 2009
Externally published	Yes

Keywords

Cascade reactions
Complexe reactions
Electrospray mass spectrometry
Iminium catalysis
Organocatalysis

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10.1002/anie.200804353

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title = "Characterization of key intermediates in a complex organocatalytic cascade reaction using mass spectrometry",

abstract = "Chemical scrabble: Mechanistic studies of complex organocatalytic cascade reactions are challenging owing to the presence of many species involved. Electrospray ionization mass spectrometry provides details about a one-pot quadruple organocatalytic cascade reaction, and allows detailed characterization of the reaction and its key intermediates.",

keywords = "Cascade reactions, Complexe reactions, Electrospray mass spectrometry, Iminium catalysis, Organocatalysis",

author = "Wolfgang Schrader and Handayani, \{Peni Purwa\} and Jian Zhou and Benjamin List",

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AU - Schrader, Wolfgang

AU - Handayani, Peni Purwa

AU - Zhou, Jian

AU - List, Benjamin

PY - 2009/2/9

Y1 - 2009/2/9

N2 - Chemical scrabble: Mechanistic studies of complex organocatalytic cascade reactions are challenging owing to the presence of many species involved. Electrospray ionization mass spectrometry provides details about a one-pot quadruple organocatalytic cascade reaction, and allows detailed characterization of the reaction and its key intermediates.

AB - Chemical scrabble: Mechanistic studies of complex organocatalytic cascade reactions are challenging owing to the presence of many species involved. Electrospray ionization mass spectrometry provides details about a one-pot quadruple organocatalytic cascade reaction, and allows detailed characterization of the reaction and its key intermediates.

KW - Cascade reactions

KW - Complexe reactions

KW - Electrospray mass spectrometry

KW - Iminium catalysis

KW - Organocatalysis

UR - https://www.scopus.com/pages/publications/60149092311

U2 - 10.1002/anie.200804353

DO - 10.1002/anie.200804353

M3 - 文章

AN - SCOPUS:60149092311

SN - 1433-7851

VL - 48

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EP - 1466

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 8

ER -

Characterization of key intermediates in a complex organocatalytic cascade reaction using mass spectrometry

Abstract

Keywords

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