Cesium carbonate mediated borylation of aryl iodides with diboron in methanol

Jieming Zhang; Hai Hong Wu; Junliang Zhang

doi:10.1002/ejoc.201300829

Cesium carbonate mediated borylation of aryl iodides with diboron in methanol

Jieming Zhang, Hai Hong Wu, Junliang Zhang

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

68 Scopus citations

Abstract

Herein we describe the unexpected borylation of aryl iodides promoted by a Cs₂CO₃ and MeOH system. This formal nucleophilic boryl substitution could be applied to a wide range of functionalized aryl iodide compounds. The preliminary results indicate that this process is neither copper catalyzed nor radical mediated.

Original language	English
Pages (from-to)	6263-6266
Number of pages	4
Journal	European Journal of Organic Chemistry
Issue number	28
DOIs	https://doi.org/10.1002/ejoc.201300829
State	Published - Oct 2013

Keywords

Boron
Cesium
Copper
Lewis bases
Transition metals

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10.1002/ejoc.201300829

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title = "Cesium carbonate mediated borylation of aryl iodides with diboron in methanol",

abstract = "Herein we describe the unexpected borylation of aryl iodides promoted by a Cs2CO3 and MeOH system. This formal nucleophilic boryl substitution could be applied to a wide range of functionalized aryl iodide compounds. The preliminary results indicate that this process is neither copper catalyzed nor radical mediated.",

keywords = "Boron, Cesium, Copper, Lewis bases, Transition metals",

author = "Jieming Zhang and Wu, \{Hai Hong\} and Junliang Zhang",

year = "2013",

month = oct,

doi = "10.1002/ejoc.201300829",

language = "英语",

pages = "6263--6266",

journal = "European Journal of Organic Chemistry",

issn = "1434-193X",

publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - Cesium carbonate mediated borylation of aryl iodides with diboron in methanol

AU - Zhang, Jieming

AU - Wu, Hai Hong

AU - Zhang, Junliang

PY - 2013/10

Y1 - 2013/10

N2 - Herein we describe the unexpected borylation of aryl iodides promoted by a Cs2CO3 and MeOH system. This formal nucleophilic boryl substitution could be applied to a wide range of functionalized aryl iodide compounds. The preliminary results indicate that this process is neither copper catalyzed nor radical mediated.

AB - Herein we describe the unexpected borylation of aryl iodides promoted by a Cs2CO3 and MeOH system. This formal nucleophilic boryl substitution could be applied to a wide range of functionalized aryl iodide compounds. The preliminary results indicate that this process is neither copper catalyzed nor radical mediated.

KW - Boron

KW - Cesium

KW - Copper

KW - Lewis bases

KW - Transition metals

UR - https://www.scopus.com/pages/publications/84884902694

U2 - 10.1002/ejoc.201300829

DO - 10.1002/ejoc.201300829

M3 - 文章

AN - SCOPUS:84884902694

SN - 1434-193X

SP - 6263

EP - 6266

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 28

ER -

Cesium carbonate mediated borylation of aryl iodides with diboron in methanol

Abstract

Keywords

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