Catalytic enantioselective diboration of cyclic dienes. a modified ligand with general utility

Kai Hong; James P. Morken

doi:10.1021/jo201321k

Catalytic enantioselective diboration of cyclic dienes. a modified ligand with general utility

Kai Hong, James P. Morken

Boston College

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

The enantioselective 1,4-diboration of cyclic dienes with a new taddol-derived phosphonite ligand occurs with excellent enantioselectivity. Oxidation delivers the derived 1,4-diol, whereas homologation can be used to deliver a chiral 1,6-diol.

Original language	English
Pages (from-to)	9102-9108
Number of pages	7
Journal	Journal of Organic Chemistry
Volume	76
Issue number	21
DOIs	https://doi.org/10.1021/jo201321k
State	Published - 4 Nov 2011
Externally published	Yes

Access to Document

10.1021/jo201321k

Cite this

@article{ab7143bd9dcd4859a71f07de3c404072,

title = "Catalytic enantioselective diboration of cyclic dienes. a modified ligand with general utility",

abstract = "The enantioselective 1,4-diboration of cyclic dienes with a new taddol-derived phosphonite ligand occurs with excellent enantioselectivity. Oxidation delivers the derived 1,4-diol, whereas homologation can be used to deliver a chiral 1,6-diol.",

author = "Kai Hong and Morken, \{James P.\}",

year = "2011",

month = nov,

day = "4",

doi = "10.1021/jo201321k",

language = "英语",

volume = "76",

pages = "9102--9108",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Catalytic enantioselective diboration of cyclic dienes. a modified ligand with general utility

AU - Hong, Kai

AU - Morken, James P.

PY - 2011/11/4

Y1 - 2011/11/4

N2 - The enantioselective 1,4-diboration of cyclic dienes with a new taddol-derived phosphonite ligand occurs with excellent enantioselectivity. Oxidation delivers the derived 1,4-diol, whereas homologation can be used to deliver a chiral 1,6-diol.

AB - The enantioselective 1,4-diboration of cyclic dienes with a new taddol-derived phosphonite ligand occurs with excellent enantioselectivity. Oxidation delivers the derived 1,4-diol, whereas homologation can be used to deliver a chiral 1,6-diol.

UR - https://www.scopus.com/pages/publications/80055077679

U2 - 10.1021/jo201321k

DO - 10.1021/jo201321k

M3 - 文章

C2 - 21932816

AN - SCOPUS:80055077679

SN - 0022-3263

VL - 76

SP - 9102

EP - 9108

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 21

ER -

Catalytic enantioselective diboration of cyclic dienes. a modified ligand with general utility

Abstract

Access to Document

Other files and links

Fingerprint

Cite this